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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
1,1,2-Trichloroethane with Water.
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) 1,1,2-Trichloroethane; C2H3Cl3; [79-00-5]
NIST Chemistry WebBook
for detail
Original Measurements:
Newsham, D.M.T., Measurement and Correlation of Thermodynamic Data for Chlorinated Hydrocarbons, UMIST, Manchester (January. 1981).
Variables:
Temperature = 293 K
pH = pH=2-9
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
2
* Mass Fraction w
1
(compiler)
10
4
* Mole Fraction x
1
10
2
* w
1
/M
1
(compiler) [mol g**-1]
pH
20
0.413
5.60 +/- 0.06
3.10 x 10
-3
2.0
20
0.416
5.67 +/- 0.06
3.12 x 10
-3
7.3
20
0.408
5.53 +/- 0.10
3.06 x 10
-3
8.8
Method/Apparatus/Procedure:
Samples were equilibrated for at least ten days in a waterbath thermostat. The
p
H of the samples was adjusted by addition of either hydrochloric acid or sodium hydroxide. The concentration of 1,1,2-trichloroethane was determined using a Perkin-Elmer model 900 gas chromatograph equipped with a flame ionization detector and an automatic digital integrator.
Source and Purity of Materials:
(1) Source not given, contained less than 0.1% dissolved material.
(2) Distilled (compiler).
Estimated Errors:
Solubility: See table above.
Temperature: ± 0.1 K.