IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: 1,1,2-Trichloroethane with Water.

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) 1,1,2-Trichloroethane; C2H3Cl3; [79-00-5]  NIST Chemistry WebBook for detail

Original Measurements:
   Newsham, D.M.T., Measurement and Correlation of Thermodynamic Data for Chlorinated Hydrocarbons, UMIST, Manchester (January. 1981).

Variables:
   Temperature = 321 K
   Pressure = 321 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  
t/°CPressure [mm Hg]102 * Mass Fraction w1 (compiler) 104 * Mole Fraction x1
48.26.032.88 x 10-20.39
48.212.26.36 x 10-20.86
48.214.58.14 x 10-21.10
48.218.09.18 x 10-21.24
48.231.42.05 x 10-12.77
48.247.63.31 x 10-14.49
Method/Apparatus/Procedure:
   Samples were equilibrated for at least ten days in a waterbath thermostat. The concentration of 1,1,2-trichloroethane in water was determined using a Perkin-Elmer model 900 gas chromatograph equipped with a flame ionization detector and an  automatic digital integrator. A helium carrier gas and a Poropack QS column were used for the chromatographic analyses.

Source and Purity of Materials:
   (1) Source not given, contained less than 0.1% dissolved material.
   (2) Distilled (compiler).

Estimated Errors:
   Solubility: ± 1 %.
   Temperature: ± 0.1 K.