IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: 1,1,2-Trichloroethane with Water.
Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) 1,1,2-Trichloroethane; C2H3Cl3; [79-00-5]  NIST Chemistry WebBook for detail
Original Measurements:
   Leighton, D.T.; Calo, J.M., J. Chem. Eng. Data 1981, 26, 382-5.

 Variables:
   Temperature = 276 K - 299 K

 Prepared By:
   A. L. Horvath

 Experimental Data:   (Notes on the Nomenclature)
  
t/°CDistribution coefficient, DL102 * Mass Fraction w1 (compiler) 104 * Mole Fraction x1 (compiler)
2.516.670.37055.0191
7.020.960.38915.2719
12.926.910.43235.8595
18.034.140.45236.1327
19.533.640.49856.7619
24.344.610.49226.6761
26.148.470.49026.6486
 Notes:
   a  Gas-liquid system analysis parameter, from calibration measurements.

 Method/Apparatus/Procedure:
   A 5 μL 1,1,2-trichloroethane sample was injected into a 2.3 dm3 equilibration cell containing distilled water. After the cell was shaken vigorously for about 5 minutes, the homogeneity of the liquid sample was maintained with a  magnetic stirrer. Compressed air was passed through the cell and the gas flow was measured with a soap film flowmeter. The 1,1,2-trichloroethane content was extracted and analyzed using a dual flame ionization detector gas chromatograph.

 Source and Purity of Materials:
   (1) Source and purity not given.
   (2) Distilled.

 Estimated Errors:
   Solubility: ± 10 %.
   Temperature: ± 0.5 K.