IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Tetrachloroethene (tetrachloroethylene) with Water.

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Tetrachloroethene (tetrachloroethylene); C2Cl4; [127-18-4]  NIST Chemistry WebBook for detail

Original Measurements:
   Moiseeva, L.M.; Stepanova, G.G.; Pukhonto, A.N., Sov. Chem. Ind. 9, 453 (1977).

Variables:
   Temperature = 293 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  
t/°CDensity ρ [kg m**-3]102 * Mass Fraction w1 (compiler) 105 * Mole Fraction x1 (compiler)
200.20652.069 x 10-22.25
Method/Apparatus/Procedure:
   Water was saturated with tetrachloroethene in a thermostatted round bottomed flask fitted with a stirrer and a mercury seal. The stirring was continued for several days until equilibrium between the two liquids was established. The analysis of the  saturated aqueous solution was carried out using a gas chromatograph. The column was filled with Cromosorb W, impregnated with Apiezon I. The helium carrier gas flow rate was 500 cm3/minute.

Source and Purity of Materials:
   (1) Type "pure" (METU 6-00 No. 6590-70), redistilled and checked by GLC.
   (2) Distilled.

Estimated Errors:
   Solubility: ± 1.74 %.
   Temperature: ± 0.2 K.