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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
1,1,2-Trichloroethane with Water.
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) 1,1,2-Trichloroethane; C2H3Cl3; [79-00-5]
NIST Chemistry WebBook
for detail
Original Measurements:
Wright, D.A.; Sandler, S.I.; DeVoll, D., Environ. Sci. Technol. 1992, 26, 1828-31.
Variables:
Temperature = 293 K - 323 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
γ
∞
1
10
2
* Mass Fraction w
1
(compiler)
10
4
* Mole Fraction x
1
20
1520+/-10
0.485
6.58
35
1410+/-125
0.523
7.09
50
1220+/-20
0.604
8.20
Method/Apparatus/Procedure:
A differential static cell equilibrium apparatus was used to measure the infinite dilution activity coefficient of 1,1,2-trichloroethane in water. Cells containing degassed water were submerged in a thermostat water bath. The 1,1,2-trichloroethane was injected into the mixture cells and a magnetic stirrer was turned on. Then, the cells were allowed to equilibrate. The stirrer was then turned off and the differential pressure was recorded. The experiment was repeated at least three times at each temperature.
Source and Purity of Materials:
(1) Source and purity not given.
(2) Distilled, filtered and deionized
Estimated Errors:
Solubility: Not specified.
Temperature: ± 0.5 K.