IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: 1,2-Dibromoethane with Water.

Components:
   (1) 1,2-Dibromoethane; C2H4Br2; [106-93-4]  NIST Chemistry WebBook for detail
   (2) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail

Original Measurements:
   Tokoro, R.; Bilewicz, R.; Osteryoung, J., Anal. Chem. 58, 1964 (1986).

Variables:
   Temperature = 298 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  
t/°C103 * g1/g2102 * Mass Fraction w1 (compiler) 104 * Mole Fraction x1 (compiler)
253.120.3112.99
Method/Apparatus/Procedure:
   A saturated aqueous solution of 1,2-dibromoethane was filtered and samples of 50, 100, and 200 μL were diluted in a 0.1 M tetraethylammonium perchlorate aqueous solution. A cathodic voltammogram on the HMDE was recorded. Quantization was done by  standard addition using 0.01 M solute in ethanol as the standard.

Source and Purity of Materials:
   (1) Fisher Scientific Co., E173 certified, 99.5 % pure. Used as received.
   (2) Distilled.and further purified using a Millipore Milliq system.

Estimated Errors:
   Solubility: ± 4.0 x 10-5g1/g2.
   Temperature: ± 0.2 K.