IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: 1,1-Dichloroethane with Water.
Components:
   (1) 1,1-Dichloroethane; C2H4Cl2; [75-34-3]  NIST Chemistry WebBook for detail
   (2) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
Original Measurements:
   Newsham, D.M.T., Measurement and Correlation of Thermodynamic Data for Chlorinated Hydrocarbons, UMIST, Manchester (January. 1981).

 Variables:
   Temperature = 273 K - 323 K

 Prepared By:
   A. L. Horvath

 Experimental Data:   (Notes on the Nomenclature)
  
t/°C102 * Mass Fraction w1 (compiler) 102 * Mass Fraction w2 (compiler)104 * Mole Fraction x1103 * Mole Fraction x2
0.0-4.94 x 10-2-2.71 x 10-2
11.40.492-8.99-
20.00.4658.28 x 10-28.504.53
25.00.479-8.75-
30.00.4451.18 x 10-18.136.45
35.00.464-8.49-
40.0-1.54 x 10-1-8.39
50.00.4491.96 x 10-18.2110.67
 Method/Apparatus/Procedure:
   Samples were equilibrated for at least ten days in a waterbath thermostat. Water analysis was performed with an automatic Karl Fischer titration apparatus. The concentration of 1,1-dichloroethane in water was determined using a Perkin-Elmer  model 900 chromatograph equipped with a flame ionization detector and an automatic digital integrator. A helium carrier gas and a Poropack QS column were used for the chromatographic analyses.

 Source and Purity of Materials:
   (1) Source not given, contained less than 0.1 % dissolved material.
   (2) Distilled (compiler).

 Estimated Errors:
   Solubility: ± 1 %.
   Temperature: ± 0.1 K.