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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
1,1-Dichloroethane with Water.
Components:
(1) 1,1-Dichloroethane; C2H4Cl2; [75-34-3]
NIST Chemistry WebBook
for detail
(2) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
Original Measurements:
Newsham, D.M.T., Measurement and Correlation of Thermodynamic Data for Chlorinated Hydrocarbons, UMIST, Manchester (January. 1981).
Variables:
Temperature = 298 K - 321 K
Prepared By:
A. L. Horvath
Experimental Remarks:
p
1
= partial pressure of (1).
Experimental Data:
(Notes on the Nomenclature)
t/°C
Pressure [mm Hg]
10
2
* Mass Fraction w
1
(compiler)
10
4
* Mole Fraction x
1
24.5
7.10
0.113
2.06
24.5
1.050
0.184
3.36
24.5
1.499
0.278
5.08
24.5
1.922
0.369
6.74
47.5
1.817
0.120
2.19
47.5
2.270
0.146
2.66
47.5
2.821
0.202
3.68
47.5
4.123
0.309
5.64
Method/Apparatus/Procedure:
Samples were equilibrated for at least 10 days in a waterbath thermostat. The concentration of 1,1-dichloroethane was determined using a Perkin-Elmer model 900 gas chromatograph equipped with a flame ionization detector and an automatic digital integrator. A helium carrier gas and a Poropack QS column were used for the chromatographic analyses.
Source and Purity of Materials:
(1) Source not given, contained less than 0.1 % dissolved material.
(2) Distilled.
Estimated Errors:
Solubility: ± 1 %.
Temperature: ± 0.1 K.