IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: 1,1-Dichloroethane with Water.

Components:
   (1) 1,1-Dichloroethane; C2H4Cl2; [75-34-3]  NIST Chemistry WebBook for detail
   (2) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail

Original Measurements:
   Newsham, D.M.T., Measurement and Correlation of Thermodynamic Data for Chlorinated Hydrocarbons, UMIST, Manchester (January. 1981).

Variables:
   Temperature = 298 K - 321 K

Prepared By:
   A. L. Horvath

Experimental Remarks:

   p1 = partial pressure of (1).

Experimental Data:   (Notes on the Nomenclature)
  
t/°CPressure [mm Hg]102 * Mass Fraction w1 (compiler) 104 * Mole Fraction x1
24.57.100.1132.06
24.51.0500.1843.36
24.51.4990.2785.08
24.51.9220.3696.74
47.51.8170.1202.19
47.52.2700.1462.66
47.52.8210.2023.68
47.54.1230.3095.64
Method/Apparatus/Procedure:
   Samples were equilibrated for at least 10 days in a waterbath thermostat. The concentration of 1,1-dichloroethane was determined using a Perkin-Elmer model 900 gas chromatograph equipped with a flame ionization detector and an automatic digital  integrator. A helium carrier gas and a Poropack QS column were used for the chromatographic analyses.

Source and Purity of Materials:
   (1) Source not given, contained less than 0.1 % dissolved material.
   (2) Distilled.

Estimated Errors:
   Solubility: ± 1 %.
   Temperature: ± 0.1 K.