IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: 1,1-Dichloroethane with 1,1,2-Trichloroethane and Water.

   (1) 1,1-Dichloroethane; C2H4Cl2; [75-34-3]  NIST Chemistry WebBook for detail
   (2) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (3) 1,1,2-Trichloroethane; C2H3Cl3; [79-00-5]  NIST Chemistry WebBook for detail

Original Measurements:
   Newsham, D.M.T., Measurement and Correlation of Thermodynamic Data for Chlorinated Hydrocarbons, UMIST, Manchester (January. 1981).

   Temperature = 285 K - 304 K

Prepared By:
   A. L. Horvath

Experimental Remarks:

   Solubility of equimolar mixtures of 1,1-dichloroethane and 1,1,2-trichloroethane in water.

Experimental Data:   (Notes on the Nomenclature)
t/°C102 * Mass Fraction w1 (compiler) 102 * Mass Fraction w2 (compiler)104 * Mole Fraction x1104 * Mole Fraction x2
   Samples were equilibrated for at least ten days in a waterbath thermostat. The chlorinated hydrocarbons were determined using a Perkin-Elmer model 900 gas chromatograph equipped with a flame ionization detector and an automatic digital integrator.  A helium carrier gas and a Poropack QS column were used for the chromatographic analyses.

Source and Purity of Materials:
   (1) Source not given, contained less than 0.1 % dissolved material.
   (2) Source not given, contained less than 0.1 % dissolved material.
   (3) Distilled (compiler).

Estimated Errors:
   Solubility: ± 1 %.
   Temperature: ± 0.1 K.