Home
Introduction
Search Menu
IUPAC Series (PDF)
Reference
Version History
About the Project
Disclaimer
Contact Us
Acknowledgements
IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Water with 1,2-Dichloroethane.
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) 1,2-Dichloroethane; C2H4Cl2; [107-06-2]
NIST Chemistry WebBook
for detail
Original Measurements:
Christian, S.D.; Affsprung, H.E.; Hunter, W.J.A.; Gillam, W.S.; McCoy, W.H., Solute Properties of Water, U. S. Office of Saline Water Research and Development Program, Report No. 301 1968, p. 71, 79.
Variables:
Temperature = 283 K - 308 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
2
* Mass Fraction w
1
(compiler)
10
3
* Mole Fraction x
1
(compiler)
n
1
/V
2
[mol m**-3]
10
0.115
6.30
0.0812 +/- 0.0010
25
0.182
9.94
0.1262 +/- 0.0014
35
0.230
12.49
0.1570 +/- 0.0016
Method/Apparatus/Procedure:
The solute isopiestic method was used without modification. The apparatus employed consisted of a closed vessel divided into two compartments, one for water and the other for the organic solvent. Equilibrium was attained after a period of 6 to 8 hours. Samples of the solution were analyzed for water with the Beckman KF-Aquameter. The Karl Fischer reagent was standardized against crystalline sodium tartarate dihydrate.
Source and Purity of Materials:
(1) Distilled.
(2) Certified or regant grade, distilled through a 30 plate Oldershaw column before use.
Estimated Errors:
Solubility: See table above.
Temperature: ± 0.1 K.