IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: 2-Bromo-2-chloro-1,1,1-trifluoroethane with Water.

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) 2-Bromo-2-chloro-1,1,1-trifluoroethane; C2HBrClF3; [151-67-7]  NIST Chemistry WebBook for detail

Original Measurements:
   Halliday, M.M.; MacDonald, I.; MacGregor, M.H.G., Br. J. Anaest. 49, 413 (1977).

Variables:
   Temperature = 310 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  
t/°COstwald coefficient, L /dimensionless102 * Mass Fraction w1 (compiler) 104 * Mole Fraction x1 (compiler)
36.850.800.3893.56
Method/Apparatus/Procedure:
   A steady flow of anaesthetic vapor was bubbled through water, allowing 45 minutes for equilibration. The concentration in the gas mixture was in the range 1-3 % (v/v) 2-bromo-2-chloro-1,1,1-tri-fluoroethane. A Riken 18A refractometer provided  accurate estimations of the gaseous concentrations of 2-bromo-2-chloro-1,1,1-trifluoroethane. Five samples of aqueous solutions were analyzed by gas chromatography. The chromatograph was equipped with a flame ionization detector and a potentiometric recorder.

Source and Purity of Materials:
   (1) ICI Pharmaceuticals, used as received.
   (2) Distilled.

Estimated Errors:
   Solubility: ± 0.01 SEM.
   Temperature: ± 0.5 K (compiler).