IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: 1,1,2,3,4,4-Hexachloro-1,3-butadiene with Water
Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) 1,1,2,3,4,4-Hexachloro-1,3-butadiene; C4Cl6; [87-68-3]  NIST Chemistry WebBook for detail
Original Measurements:
   Antropov, L.I.; Populyai, V.E.; Simonov, V.D.; Shamsutdinov, T.M., Russ. J. Phys. Chem. 1972, 46, 311-2 (VINITI No. 3739-71).

 Variables:
   Temperature = 288 K - 299 K

 Prepared By:
   A. L. Horvath

 Experimental Data:   (Notes on the Nomenclature)
  
t/°C102 * Mass Fraction w1102 * Mass Fraction w2107 * Mole Fraction x1 (compiler)104 * Mole Fraction x2 (compiler)
153.2 x 10-4- x 1002.21-
18- x 1000.834 x 10-3-1.21
203.8 x 10-4- x 1002.62-
22- x 1001.25 x 10-3-1.66
264.12 x 10-45.65 x 10-32.858.17
 Method/Apparatus/Procedure:
   The Alexejew's synthetic method of solubility determination was used.1 A fixed weight of 1,1,2,3,4,4-hexachloro-1,3-butadiene and water was sealed in a tube and subjected to gradually increasing temperature  with constant agitation. The appearance of an opalescence or clouding was an indication of saturation temperature. The temperature was then allowed to fall and an observation made, while the tube was constantly agitated, to  establish the temperature of the first appearance of opalescence. The observation was repeated several times.

 Source and Purity of Materials:
   (1) Synthesized by the authors, purified by fractional distillation and dried with CaCl2 and P2O5.
   (2) Distilled.

 Estimated Errors:
   Solubility: Not specified.
   Temperature: ± 1 K (compiler).

 References:
   1 W. Alexejew, Ann. Phys. Chem. 28, 305 (1886).