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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
1,1,2,3,4,4-Hexachloro-1,3-butadiene with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) 1,1,2,3,4,4-Hexachloro-1,3-butadiene; C4Cl6; [87-68-3]
NIST Chemistry WebBook
for detail
Original Measurements:
Banerjee, S.; Yalkowsky, S.H.; Valvani, S.C., Environ. Sci. Technol. 1980, 14, 1227-9.
Variables:
Temperature = 298 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
6
* Concentration c
1
[mol dm**3]
10
2
* Mass Fraction w
1
(compiler)
10
7
* Mole Fraction x
1
(compiler)
25
12.4
3.24 x 10
-4
2.20
Method/Apparatus/Procedure:
An excess of 1,1,2,3,4,4-hexachloro-1,3-butadiene was added to a stainless steel tube containing water and the tube was sealed. It was allowed to equilibrate during shaking for a week at 25°C. After centrifugation, the sample was analyzed for radioactivity using a liquid scintillation counting. The solubility determination was repeated at least twice for each sample and the analysis was done in duplicate.
Source and Purity of Materials:
(1) New England Nuclear, used as received.
(2) Distilled.
Estimated Errors:
Solubility: ± 2.5 %.
Temperature: ± 0.3 K.