IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: 4-Bromo-1-butene with Water
Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) 4-Bromo-1-butene; C4H7Br; [5162-44-7]  NIST Chemistry WebBook for detail
Original Measurements:
   Tewari, Y.B.; Miller, M.M.; Wasik, S.P.; Martire, D.E., J. Chem. Eng. Data 1982, 27, 451-4.

 Variables:
   Temperature = 298 K

 Prepared By:
   A. L. Horvath

 Experimental Data:   (Notes on the Nomenclature)
  
t/°CConcentration c1 [mol dm**-3]102 * Mass Fraction w1 (compiler) 104 * Mole Fraction x1 (compiler)
255.66 x 10-37.63 x 10-21.02
 Method/Apparatus/Procedure:
   The modified generator column method was used. A chromatographic column was coated with liquid 4-bromo-1-butene. An aqueous phase was generated by pumping water through the coated generator column. The  aqueous solution was analyzed by a high pressure liquid chromatographic method which has been described elsewhere.1 The result is an average of at least three measurements.

 Source and Purity of Materials:
   (1) Source not given. At least 99 % pure by GC analysis.
   (2) Baker-analysed HPLC grade.

 Estimated Errors:
   Solubility: ± 1.0 %.
   Temperature: ± 0.1 K.

 References:
   1 H. DeVoe, M. M. Miller, and S. P. Wasik, J. Res. Natl. Bur. Stand. 86, 361 (1981).