IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: 1,4-Dichlorobutane with Water
Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) 1,4-Dichlorobutane; C4H8Cl2; [110-56-5]  NIST Chemistry WebBook for detail
Original Measurements:
   Leighton, D.T.; Calo, J.M., J. Chem. Eng. Data 1981, 26, 382-5.

 Variables:
   Temperature = 287 K - 298 K

 Prepared By:
   A. L. Horvath

 Experimental Data:   (Notes on the Nomenclature)
  
t/°CDistribution coefficient, DL102 * Mass Fraction w1 (compiler) 104 * Mole Fraction x1 (compiler)
13.515.270.12011.705
15.720.050.10441.482
17.121.350.10821.536
22.024.760.12831.822
24.926.610.15742.236
 Notes:
   a  Gas-liquid system analysis parameter, from calibration measurements.

 Method/Apparatus/Procedure:
   A 5 μL 1,4-Dichlorobutane sample was injected into a 2.3 dm3 equilibration cell containing distilled water. After the cell was shaken vigorously for about 5 minutes, the homogeneity of the liquid sample was  maintained with a magnetic stirrer. Compressed air was passed through the cell and the gas flow was measured with a soap film flowmeter. The 1,4-Dichlorobutane content was extracted and analyzed using a  dual flame ionization detector gas chromatograph.

 Source and Purity of Materials:
   (1) Source and purity not given.
   (2) Distilled.

 Estimated Errors:
   Solubility: ± 6.1 %.
   Temperature: ± 0.5 K.