IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: 1-Chlorobutane with Water
Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) 1-Chlorobutane; C4H9Cl; [109-69-3]  NIST Chemistry WebBook for detail
Original Measurements:
   Leighton, D.T.; Calo, J.M., J. Chem. Eng. Data 1981, 26, 382-5.

 Variables:
   Temperature = 274 K - 296 K

 Prepared By:
   A. L. Horvath

 Experimental Data:   (Notes on the Nomenclature)
  
t/°CDistribution coefficient, DL102 * Mass Fraction w1 (compiler) 104 * Mole Fraction x1 (compiler)
1.0325.56.241 x 10-21.2153
3.0375.36.050 x 10-21.1780
12.4536.96.992 x 10-21.3616
12.5569.26.596 x 10-21.2843
17.9693.47.115 x 10-21.3855
19.1738.27.014 x 10-21.3659
22.7833.97.331 x 10-21.4276
23.08397.458 x 10-21.4524
 Notes:
   a  Gas-liquid system analysis parameter, from calibration measurements.

 Method/Apparatus/Procedure:
   A 5 μL 1-chlorobutane sample was injected into a 2.3 dm3 equilibration cell containing distilled water. After the cell was shaken vigorously for about 5 minutes, the homogeneity of the liquid sample was  maintained with a magnetic stirrer. Compressed air was passed through the cell and the gas flow was measured with a soap film flowmeter. The 1-chlorobutane content  was extracted and analyzed using a dual flame ionization detector gas chromatograph.

 Source and Purity of Materials:
   (1) Source and purity not given.
   (2) Distilled.

 Estimated Errors:
   Solubility: ± 2.1 %.
   Temperature: ± 0.5 K.