IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: 1,1,1,2,2,3,3,4,5,5,5-Undecafluoro-4-(tri-fluoromethyl)-pentane with Water

   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) 1,1,1,2,2,3,3,4,5,5,5-Undecafluoro-4-(tri-fluoromethyl)-pentane; C6F14; [355-04-4]  NIST Chemistry WebBook for detail

Original Measurements:
   Kabal'nov, A.S.; Makarov, K.N.; Shcherbakova, O.V., J. Fluorine Chem. 50, 271-84 (1990).

   Temperature = 298 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
t/°CConcentration c1 [mol dm**-3]102 * Mass Fraction w1 (compiler) 109 * Mole Fraction x1 (compiler)
255.0 x 10-71.69 x 10-59.01
   The solubility values were calculated from the particle size growth in emulsions due to Ostwald ripening. The particle size analysis of emulsions was accomplished through the use of a photon correlation spectrometer. The  kinetics of particle size growth were observed until a 200 nm diameter was attained. The solubility measurement method showed a very low detection limit. Further details on Ostwald ripening kinetics are described elsewhere.1

Source and Purity of Materials:
   (1) Source not given. Commercial grade, 97 % pure.
   (2) Doubly distilled and deionized.

Estimated Errors:
   Solubility: About ± 30 %.
   Temperature: ± 1.0 K.

   1 P. W. Voorhees, J. Stat. Phys. 38, 231 (1985).