IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Tetradecafluorohexane with Water
Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Tetradecafluorohexane; C6F14; [355-42-0]  NIST Chemistry WebBook for detail
Original Measurements:
   Kabal'nov, A.S.; Makarov, K.N.; Shcherbakova, O.V., J. Fluorine Chem. 50, 271-84 (1990).

 Variables:
   Temperature = 298 K

 Prepared By:
   A. L. Horvath

 Experimental Data:   (Notes on the Nomenclature)
  
t/°CConcentration c1 [mol dm**-3]102 * Mass Fraction w1 (compiler) 109 * Mole Fraction x1 (compiler)
252.7 x 10-79.13 x 10-64.86
 Method/Apparatus/Procedure:
   The solubility values were calculated from the particle size growth in emulsions due to Ostwald ripening. The particle size analysis of emulsions was accomplished through the use of a photon correlation spectrometer. The  kinetics of particle size growth were observed until a 200 nm diameter was attained. The solubility measurement method showed a very low detection limit. Further details on Ostwald ripening kinetics are described elsewhere.1

 Source and Purity of Materials:
   (1) Source not given. Commercial grade, 99 % pure.
   (2) Doubly distilled and deionized.

 Estimated Errors:
   Solubility: About +/- 30%
   Temperature: ± 1.0 K.

 References:
   1 P. W. Voorhees, J. Stat. Phys. 38, 231 (1985).