IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: 1-Chlorohexane with Water
Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) 1-Chlorohexane; C6H13Cl; [544-10-5]  NIST Chemistry WebBook for detail
Original Measurements:
   Leighton, D.T.; Calo, J.M., J. Chem. Eng. Data 1981, 26, 382-5.

 Variables:
   Temperature = 274 K - 296 K

 Prepared By:
   A. L. Horvath

 Experimental Data:   (Notes on the Nomenclature)
  
t/°CDistribution coefficient, DL102 * Mass Fraction w1 (compiler) 106 * Mole Fraction x1 (compiler)
1399.53.687 x 10-35.507
3365.54.946 x 10-37.387
12.4668.35.645 x 10-38.432
12.5728.45.248 x 10-37.839
17.9873.26.187 x 10-39.241
19.1969.75.929 x 10-38.855
22.71161.46.237 x 10-39.316
23.01267.75.783 x 10-38.638
 Notes:
   a  Gas-liquid system analysis parameter, from calibration measurements.

 Method/Apparatus/Procedure:
   A 5 μL 1-chlorohexane sample was injected into a 2.3 dm3 equilibration cell containing distilled water. After the cell was shaken vigorously for about 5 minutes, the homogeneity of the liquid sample was  maintained with a magnetic stirrer. Compressed air was passed through the cell and the gas flow was measured with a soap film flowmeter. The 1-chlorohexane content  was extracted and analyzed using a dual flame ionization detector gas chromatograph.

 Source and Purity of Materials:
   (1) Source and purity not given.
   (2) Distilled.

 Estimated Errors:
   Solubility: ± 5.8 %.
   Temperature: ± 0.5 K.