IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Octadecafluorooctane with Water

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Octadecafluorooctane; C8F18; [307-34-6]  NIST Chemistry WebBook for detail

Original Measurements:
   Markina, Z.N.; Zadymova, N.M.; Shchukin, E.D.; Makarov, K.N.; Gervits, L.L., Zh. Vses. Khim. O-Va. im. D. I. Mendeleeva 33, 344-6 (1988).

Variables:
   Temperature = 293 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  
t/°CConcentration c1 [mol dm**-3]102 * Mass Fraction w1107 * Mole Fraction x1
202.3 x 10-51.0 x 10-34.15
Method/Apparatus/Procedure:
   The colloid chemical method was used for observing the shift in the critical micelle concentration formation for a surfactant in aqueous solutions under the influence of halogenated hydrocarbons. The solubility was  calculated from the increment of standard chemical potential for the transfer of a fluoromethylene group from water into the fluorocarbon phase on the basis of experimental determination of the surface  activity of a perfluoroorganic surface active nonelectrolyte.

Source and Purity of Materials:
   (1) Source and purity not given.
   (2) Distilled (compiler).

Estimated Errors:
   Solubility: Not specified.
   Temperature: ± 1 K (compiler).