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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Octadecafluorooctane with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Octadecafluorooctane; C8F18; [307-34-6]
NIST Chemistry WebBook
for detail
Original Measurements:
Markina, Z.N.; Zadymova, N.M.; Shchukin, E.D.; Makarov, K.N.; Gervits, L.L., Zh. Vses. Khim. O-Va. im. D. I. Mendeleeva 33, 344-6 (1988).
Variables:
Temperature = 293 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
Concentration c
1
[mol dm**-3]
10
2
* Mass Fraction w
1
10
7
* Mole Fraction x
1
20
2.3 x 10
-5
1.0 x 10
-3
4.15
Method/Apparatus/Procedure:
The colloid chemical method was used for observing the shift in the critical micelle concentration formation for a surfactant in aqueous solutions under the influence of halogenated hydrocarbons. The solubility was calculated from the increment of standard chemical potential for the transfer of a fluoromethylene group from water into the fluorocarbon phase on the basis of experimental determination of the surface activity of a perfluoroorganic surface active nonelectrolyte.
Source and Purity of Materials:
(1) Source and purity not given.
(2) Distilled (compiler).
Estimated Errors:
Solubility: Not specified.
Temperature: ± 1 K (compiler).