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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Hexacosafluorododecane with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Hexacosafluorododecane; C12F26; [307-59-5]
NIST Chemistry WebBook
for detail
Original Measurements:
Markina, Z.N.; Zadymova, N.M.; Shchukin, E.D.; Makarov, K.N.; Gervits, L.L., Kolloidnyi Zh. 49, 1084-9 (1987).
Variables:
Temperature = 293 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
Concentration c
1
[mol dm**-3]
10
2
* Mass Fraction w
1
10
10
* Mole Fraction x
1
19.85
1.5 x 10
-8
9.6 x 10
-7
2.7
Method/Apparatus/Procedure:
The solubility of hexacosafluorododecane in water was determined through the use of precision tensiometric measurements for aqueous solutions of perfluorononane acid on its interface with perfluorodecalin at 293 K. The measurements served as a basis for evaluation of the increment of the standard chemical potential for the transition of a perfluoromethylene group from the water phase into a perfluoroorganic liquid phase.
Source and Purity of Materials:
(1) Source and purity not given.
(2) Distilled (compiler).
Estimated Errors:
Solubility: Not specified.
Temperature: ± 0.5 K.