IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: 1-Chlorotetradecane with Water

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) 1-Chlorotetradecane; C14H29Cl; [2425-54-9]  NIST Chemistry WebBook for detail

Original Measurements:
   Staverman, A.J., Ph. D. thesis, University of Leiden, Leiden, 159 (1938)

Variables:
   Temperature = 298 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  
t/°C102 * Mass Fraction w1103 * Mole Fraction x1102 * w1/M1 (compiler) [mol g**-1]
252.32 x 10-23.281.29 x 10-3
Method/Apparatus/Procedure:
   Water was shaken with 1-chlorotetradecane for about 12 hours in a paraffin liquid bath thermostat. The water content of the organic phase was determined by the Karl Fischer  titration method. All measurements were carried out in duplicate. A full description of the method used is given in the doctoral dissertation.

Source and Purity of Materials:
   (1) Distilled.
   (2) Source and purity not given.

Estimated Errors:
   Solubility: Not specified.
   Temperature: ± 0.5 K (compiler).