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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
3-Bromo-1-propene with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) 3-Bromo-1-propene; C3H5Br; [106-95-6]
NIST Chemistry WebBook
for detail
Original Measurements:
Miller, M.M.; Wasik, S.P.; Huang, G.L.; Shiu, W.Y.; Mackay, D., Environ. Sci. Technol. 1985, 19, 522-529.
Variables:
Temperature = 298 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
2
* Mass Fraction w
1
(compiler)
10
4
* Mole Fraction x
1
(compiler)
n
1
/V
2
[mol m**-3]
25
0.383
5.72
31.7
Method/Apparatus/Procedure:
A saturated aqueous solution was prepared by passing of water through a column which was packed with glass beads coated with 3-bromo-1-propene. The saturated solution was then pumped through an extractor column and 3-bromo-1-propylene was extracted directly into an analytical column. The samples were analyzed with a liquid chromatograph equipped with both an UV absorbance and a fluorescence detector with excitation filters. The peak area was established using a Hewlett-Packard recorder.
Source and Purity of Materials:
(1) Eastman Kodak Company, commercial quality, used as received.
(2) Double distilled.
Estimated Errors:
Solubility: Not specified.
Temperature: ± 1 K (compiler).