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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
1,2,3-Trichloropropane with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) 1,2,3-Trichloropropane; C3H5Cl3; [96-18-4]
NIST Chemistry WebBook
for detail
Original Measurements:
Leighton, D.T.; Calo, J.M., J. Chem. Eng. Data 1981, 26, 382-5.
Variables:
Temperature = 275 K - 298 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
Distribution coefficient, D
L
10
2
* Mass Fraction w
1
(compiler)
10
4
* Mole Fraction x
1
(compiler)
1.9
11.66
7.230 x 10
-2
0.8841
13.5
11.46
1.651 x 10
-1
2.021
15.7
13.55
1.596 x 10
-1
1.953
17.1
14.18
1.683 x 10
-1
2.060
22
15.12
2.173 x 10
-1
2.661
24.9
19.81
2.000 x 10
-1
2.448
Notes:
a
Gas-liquid system analysis parameter, from calibration measurements.
Method/Apparatus/Procedure:
5 μL 1,2,3-trichloropropane sample was injected into a 2.3 dm
3
equilibration cell containing distilled water. After the cell was shaken vigorously for about 5 minutes, the homogeneity of the liquid sample was maintained with a magnetic stirrer. Compressed air was passed through the cell and the gas flow was measured with a soap film flowmeter. The 1,2,3-trichloropropane content was extracted and analyzed using a dual flame ionization detector gas chromatograph.
Source and Purity of Materials:
(1) Source and purity not given.
(2) Distilled.
Estimated Errors:
Solubility: ± 6.1 %.
Temperature: ± 0.5 K.