IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: 1,2,3-Trichloropropane with Water

   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) 1,2,3-Trichloropropane; C3H5Cl3; [96-18-4]  NIST Chemistry WebBook for detail

Original Measurements:
   Leighton, D.T.; Calo, J.M., J. Chem. Eng. Data 1981, 26, 382-5.

   Temperature = 275 K - 298 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
t/°CDistribution coefficient, DL102 * Mass Fraction w1 (compiler) 104 * Mole Fraction x1 (compiler)
1.911.667.230 x 10-20.8841
13.511.461.651 x 10-12.021
15.713.551.596 x 10-11.953 x 10-12.060
2215.122.173 x 10-12.661
24.919.812.000 x 10-12.448
   a  Gas-liquid system analysis parameter, from calibration measurements.

    5 μL 1,2,3-trichloropropane sample was injected into a 2.3 dm3 equilibration cell containing distilled water. After the cell was shaken vigorously for about 5 minutes, the homogeneity of the liquid sample was  maintained with a magnetic stirrer. Compressed air was passed through the cell and the gas flow was measured with a soap film flowmeter. The 1,2,3-trichloropropane content was extracted and analyzed using a  dual flame ionization detector gas chromatograph.

Source and Purity of Materials:
   (1) Source and purity not given.
   (2) Distilled.

Estimated Errors:
   Solubility: ± 6.1 %.
   Temperature: ± 0.5 K.