IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: 1,2-Dichloropropane with Water

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) 1,2-Dichloropropane; C3H6Cl2; [78-87-5]  NIST Chemistry WebBook for detail

Original Measurements:
   McNally, M.E.; Grob, R.L., J. Chromatogr. 1983, 260, 23-32.

Variables:
   Temperature = 303 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  
t/°C106 * Mass Fraction w1102 * Mass Fraction w1 (compiler) 104 * Mole Fraction x1 (compiler)
302.4204 x 1030.24153.858
Method/Apparatus/Procedure:
   Standard solutions were prepared in 100 cm3 flask. They were shaken for 5 minutes and then allowed to equilibrate in a constant temperature bath held at 30°C for 24 hours. Samples were pipetted in headspace vials,  sealed, thermostated and then examined by the gas chromatographic head space analysis technique. An F & M model 402 gas chromatograph, equipped with dual columns and dual flame ionization detectors, was used.

Source and Purity of Materials:
   (1) Chemical Service, West Chester, PA., USA, purest grade available.
   (2) Distilled and run through two Barnstead purification cartridges.

Estimated Errors:
   Solubility: ± 10.36 % rel. err.
   Temperature: ± 0.5 K (compiler).