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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
1,3-Dichloropropane with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) 1,3-Dichloropropane; C3H6Cl2; [142-28-9]
NIST Chemistry WebBook
for detail
Evaluator:
A. L. Horvath
Critical Evaluation:
The solubility of 1,3-dichloropropane (1) in water (2) has been studied by six work groups; whereas, the solubility of water (2) in 1,3-dichloropropane (1) has not been investigated yet.
All the data of six laboratories were compiled or used for the smoothing equation. The combined data points of Gross,
1
of Wright and Schaffer,
2
of Gross et al.,
3
of Chitwood,
4
of Leighton and Calo,
5
and of Bauduin et al.
6
were correlated to obtain the following mass percent (1) equation:
Solubility [100 w
1
] = - 0.64093 + 3.08718x10
-3
(T/K)
which yielded a standard deviation of 7.67x10
-3
in the temperature range from 275 to 303 K.
The curve obtained from the smoothing equation does not show a minimum over the temperature interval under examination as shown in
Fig. 4
. The conditions for the appearance of the solubility minimum are discussed in the Preface.
The tentative solubility values for this system in weight percent and mole fraction are given in Table 14, as smoothed values at 5 K intervals.
Experimental Data:
(Notes on the Nomenclature)
Table 14. Tentative solubility of 1,3-dichloroprane (1) in water (2)
t/°C
T/K
10
2
* Mass Fraction w
1
10
4
* Mole Fraction x
1
5
278.15
218 x 10
-1
3.48
10
283.15
2.33 x 10
-1
3.72
15
288.15
2.49 x 10
-1
3.98
20
293.15
2.64 x 10
-1
4.22
25
298.15
2.80 x 10
-1
4.48
30
303.15
2.95 x 10
-1
4.72
View Figure 1 for this Evaluation
References: (Click a link to see its experimental data associated with the reference)
1
Gross, P.M., J. Am. Chem. Soc. 1929, 51, 2362-6.
2
Wright, W.H.; Schaffer, J.M., Am. J. Hygiene 16, 325 (1932).
4
Chitwood, B.G., Adv. in Chem. Ser., Am. Chem. Soc., 1952, 7, 91-9.
4
Chitwood, B.G., Adv. in Chem. Ser., Am. Chem. Soc., 1952, 7, 91-9.
5
Leighton, D.T.; Calo, J.M., J. Chem. Eng. Data 1981, 26, 382-5.
6
Bauduin, G.; Bondon, D.; Gonzales-Moran, J.; Pietrasanta, Y., Analusis 13, 124-7 (1985).