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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Xenon with Poly(y-alkyl-L-glutamate) (PELG)
Components:
(1) Poly(n-alkyl-L-glutamate) (LI); ; []
NIST Chemistry WebBook
for detail
(2) Xenon; Xe; [7440-63-3]
NIST Chemistry WebBook
for detail
Original Measurements:
T. Yoshida, A. Takizawa and Y. Ysujita, J. Appl. Polym. Sci. 22, 279 (1978).
Variables:
Temperature = 293 K
Pressure = 6.6-52.5 kPa
Prepared By:
Yu. P. Yampol'skii
Experimental Data:
(Subscripts 1,2,3, ..., in column headings refer to components 1,2,3, ...)
View Figure 1 for this Evaluation
Method/Apparatus/Procedure:
Cahn electrobalance was used to measure sorption. Corresponding state principle was applied for calculation of fugacity ratio.
1,2
Source and Purity of Materials:
Xe: purity 99.999 %. Poly(
n
-alkyl-
L
-glutamates) and alkyls C
3
-C
3
prepared according to Ref. 3 by ester exchange method, Other alkyl derivatives: Kyuowa Hakko K. K. and Ajimoto Co.; degree of polymerization 1150.
Estimated Errors:
Solubility: Weight determination accuracy: ±10 mg for 50—100 rug samples.
Temperature: Precision in T: ± 0.5 K.
References:
1
T. H. Hildebrand and P.. Scott, The Solubility of Noneletrolytes (New York, 1964).
2
T. M. Prausnitz, J. Phys. Chem. 66, 640 (1962).
3
A. Tskizawa, H. Okada, S. Kadota, and H. Nonovama, J. Appl. Polym. Sci. 18. 1443 (1974).