Home
Introduction
Search Menu
IUPAC Series (PDF)
Reference
Version History
About the Project
Disclaimer
Contact Us
Acknowledgements
IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Helium with Nitrogen, Oxygen, Carbon dioxide, Methane and Polypyrrolone
Components:
(1) Helium with Nitrogen, Oxygen, Carbon dioxide, Methane; He, N2, O2, CO2, CH4; [7440-59-7, 7727-37-9, 7782-44-7, 124-38-9, 74-82-8]
NIST Chemistry WebBook
for detail
(2) Polypyrrolone; ; [12634-94-7]
NIST Chemistry WebBook
for detail
Original Measurements:
D.R.B. Walker and W.J. Koros, J. Membr. Sci., 55, 99-117 (1991).
Variables:
Temperature = 308 K
Pressure = 0.3-1.0 MPa
Prepared By:
Yu. P. Yampol'skii
Experimental Data:
(Subscripts 1,2,3, ..., in column headings refer to components 1,2,3, ...)
Solubility coefficient S /cm
3
(STP)/cm
3
atm
Chemical Name
Keunen coefficient, S
He
0.091
N2
0.72 ± 0.08
O2
1.04
CO2
4.41
CH4
1.7
Method/Apparatus/Procedure:
Pressure decay method and apparatus was used.
Source and Purity of Materials:
The polymer was synthesized according to ref. (1). It had a density 1.405 g/cc. All the gases were Linde UHP (purity more than 99.97 %).
Estimated Errors:
References:
1
Foster, R.T.; Marvel C.S. J. Polym. Sci., A, 1965, 3, 417.