IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Diiodomethene with Nitromethane

   (1) Nitromethane; CH3NO2; [75-52-5]  NIST Chemistry WebBook for detail
   (2) Diiodomethane; CH2I2; [75-11-6]  NIST Chemistry WebBook for detail

Original Measurements:
   Sazonov, V.P.; Zhilyaeva, I. N.; Gudkina, L.V., Zh. Prikl. Khim. (Leningrad) 48, 1953-7 (1975).

   Temperature = 284 K to 321 K

Prepared By:
   N. V. Sazonov and V. P. Sazonov

Experimental Data:   (Notes on the Nomenclature)
t/°CT/K102 * Mass Fraction w1Mole Fraction x1 (compiler)Comment(s)
11.00284.1530.020.0891Nitromethane-rich phase
11.00284.1597.020.8812Diodomethane-rich phase
29.22302.3742.420.1438Nitromethane-rich phase
29.22302.37--Diodomethane-rich phase
36.40309.55--Nitromethane-rich phase
36.40309.5591.590.7128Diodomethane-rich phase
36.57309.7249.810.1844Nitromethane-rich phase
36.57309.72--Diodomethane-rich phase
43.81316.9659.630.2518Nitromethane-rich phase
43.81316.96--Diodomethane-rich phase
46.32319.47--Nitromethane-rich phase
46.32319.4784.990.5634Diodomethane-rich phase
46.57319.7265.000.2974Nitromethane-rich phase
46.57319.72--Diodomethane-rich phase
47.52320.6770.000.3472Hydrocarbon-rich phase
47.52320.6779.970.4764Diodomethane-rich phase
47.87321.02--Hydrocarbon-rich phase
47.87321.0274.960.4056Diodomethane-rich phase
   The synthetic method of Alekseev was used. No further details were reported.

Source and Purity of Materials:
   (1) Source not specified; analytical purity; fractionally distilled at about 0.27 kPa; d(20 °C) = 3321.4 g·L–1.
   (2) Source not specified; pure grade reagent; distilled over a column of 15 theoretical plates; n(20 °C,D) = 1.3819, d(20 °C) = 1130 g·L–1.

Estimated Errors:
   Solubility: Not specified.
   Temperature: Not specified.
   Pressure: Not specified.