IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Nitromethane with 1,2-Ethanediol
Components:
   (1) Nitromethane; CH3NO2; [75-52-5]  NIST Chemistry WebBook for detail
   (2) 1,2-Ethanediol; C2H6O2; [107-21-1]  NIST Chemistry WebBook for detail
Original Measurements:
   Markuzin, N.P.; Nikanorova, L.A., Zh. Obshch. Khim. 32, 3469 (1962).

 Variables:
   Temperature = 301 K and 313 K

 Prepared By:
   V. P. Sazonov

 Experimental Data:   (Notes on the Nomenclature)
  
Mutual solubility of nitromethane and 1,2-ethanediol
t/°CT/K102 * Mass Fraction w1Mole Fraction x1 (compiler)Comment(s)
28.0301.237.70.381Glycol-rich phase
28.0301.291.90.920Nitromethane-rich phase
40.0313.225.30.256Glycol-rich phase
40.0313.259.00.594Nitromethane-rich phase
 Method/Apparatus/Procedure:
   The titration method was used. Solutions were mixed by stirring. The mixtures were weighed before and after the test to find the amount of added substance.

 Source and Purity of Materials:
   (1) Source not specified; pure grade reagent; distilled over a column of 20 theoretical plates; n(20 °C,D) = 1.3820, d(20 °C) = 1137.9 g·L–1.
   (2) Source not specified; pure grade reagent; purified by vacuum distillation; n(20 °C,D) = 1.4318, d(20 °C) = 1113.4 g·L­1.

 Estimated Errors:
   Solubility: 1 % (relative error).
   Temperature: control to ± 0.03 K,