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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Nitromethane with 1,2-Ethanediol
Components:
(1) Nitromethane; CH3NO2; [75-52-5]
NIST Chemistry WebBook
for detail
(2) 1,2-Ethanediol; C2H6O2; [107-21-1]
NIST Chemistry WebBook
for detail
Original Measurements:
Sazonov, V.P.; Filippov, V.V., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 18, 222-5(1975).
Variables:
Temperature = 297 K to 313 K
Prepared By:
N. V. Sazonov and V. P. Sazonov
Experimental Data:
(Notes on the Nomenclature)
Mutual solubility of nitromethane and 1,2-ethanediol
t/°C
T/K
10
2
* Mass Fraction w
1
Mole Fraction x
1
(compiler)
Comment(s)
24.15
297.30
-
-
Glycol-rich phase
24.15
297.30
92.50
0.9262
Nitromethane-rich phase
25.45
298.60
30.00
0.3035
Glycol-rich phase
25.45
298.60
-
-
Nitromethane-rich phase
29.33
302.48
-
-
Glycol-rich phase
29.33
302.48
90.00
0.9015
Nitromethane-rich phase
31.65
304.80
35.04
0.3542
Glycol-rich phase
31.65
304.80
-
-
Nitromethane-rich phase
35.58
308.73
-
-
Glycol-rich phase
35.58
308.73
85.00
0.8521
Nitromethane-rich phase
35.88
309.03
40.00
0.4040
Glycol-rich phase
35.88
309.03
-
-
Nitromethane-rich phase
37.98
311.13
44.98
0.4539
Glycol-rich phase
37.98
311.13
-
-
Nitromethane-rich phase
38.31
311.46
-
-
Glycol-rich phase
38.31
311.46
79.99
0.8025
Nitromethane-rich phase
39.21
312.36
50.03
0.5045
Glycol-rich phase
39.21
312.36
-
-
Nitromethane-rich phase
39.59
312.74
-
-
Glycol-rich phase
39.59
312.74
74.95
0.7526
Nitromethane-rich phase
39.79
312.94
54.99
0.5540
Glycol-rich phase
39.79
312.94
-
-
Nitromethane-rich phase
39.90
313.05
-
-
Glycol-rich phase
39.90
313.05
70.02
0.7037
Nitromethane-rich phase
40.01
313.16
60.00
0.6040
Glycol-rich phase
40.01
313.16
-
-
Nitromethane-rich phase
40.02
313.17
-
-
Glycol-rich phase
40.02
313.17
64.97
0.6535
Nitromethane-rich phase
40.02
313.17
62.70
0.6309
Glycol-rich phase
40.02
313.17
62.70
0.6309 (UCST)
Nitromethane-rich phase
Method/Apparatus/Procedure:
The synthetic method of Alekseev
1
was used. Close to the phase transition temperature, heating and cooling of mixtures were accomplished in steps at a rate of 0.02 K/h.
Source and Purity of Materials:
(1) Source not specified; pure grade reagent; distilled over a column of 15 theoretical plates;
n
(20 °C, D) = 1.3819,
d
(20 °C) = 1138.1 g·L
-1
.
(2) Source not specified; analytical purity; fractionally distilled at about 260 Pa;
n
(20 °C, D) = 1.4318,
d
(20 °C) = 1113.5 g·L
-1
.
Estimated Errors:
Solubility: Not reported.
Temperature: Not reported.
Pressure: Not reported.
References:
1
V. F. Alekseev, Zh. Russ. Fiz.-Khim. O-va 8, 249 (1876).