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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Nitromethane with 1-Butanol
Components:
(1) 1-Butanol; C4H10O; [71-36-3]
NIST Chemistry WebBook
for detail
(2) Nitromethane; CH3NO2; [75-52-5]
NIST Chemistry WebBook
for detail
Original Measurements:
Mel'nikova, I.K.; Dissertation, Voronezh University, 1966; Zhuravlev, E.F.; Mel'nikova, I.K., Zh. Fiz. Khim. 41, 1580-4 (1967).
Variables:
Temperature = 275 K to 291 K
Prepared By:
V. P. Sazonov
Experimental Data:
(Notes on the Nomenclature)
Mutual solubility of nitromethane and 1-butanol
t/°C
T/K
10
2
* Mass Fraction w
1
Mole Fraction x
1
(compiler)
Comment(s)
2.0
275.2
-
-
Alcohol-rich phase
2.0
275.2
87.9
0.898
Nitromethane-rich phase
6.0
279.2
20.0
0.233
Alcohol-rich phase
6.0
279.2
-
-
Nitromethane-rich phase
6.3
279.5
-
-
Alcohol-rich phase
6.3
279.5
85.0
0.873
Nitromethane-rich phase
11.0
284.2
-
-
Alcohol-rich phase
11.0
284.2
80.4
0.833
Nitromethane-rich phase
14.0
287.2
30.0
0.342
Alcohol-rich phase
14.0
287.2
-
-
Nitromethane-rich phase
15.5
288.7
-
-
Alcohol-rich phase
15.5
288.7
71.3
0.751
Nitromethane-rich phase
16.8
290.0
40.0
0.447
Alcohol-rich phase
16.8
290.0
-
-
Nitromethane-rich phase
17.0
290.2
-
-
Alcohol-rich phase
17.0
290.2
61.2
0.657
Nitromethane-rich phase
17.3
290.5
52.5
0.573
Alcohol-rich phase
17.3
290.5
-
-
Nitromethane-rich phase
17.3
290.5
53.0
0.578
Alcohol-rich phase
17.3
290.5
53.0
0.578 (UCST)
Nitromethane-rich phase
Method/Apparatus/Procedure:
The synthetic method
1
was used. No further details were reported.
Source and Purity of Materials:
(1) Source not specified; pure grade reagent; distilled; b. p = 101.3 °C at 101.33 kPa,
n
(20 °C, D) = 1.3820,
d
(20 °C) = 1132 g·L
-1
.
(2) Source not specified; pure grade reagent; distilled.
Estimated Errors:
Solubility: Not reported.
Temperature: Not reported.
Pressure: Not reported.
References:
1
V. F. Alekseev, Zh. Russ. Fiz.-Khim. O-va 8, 249 (1876).