IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Nitromethane with 1-Butanol

   (1) 1-Butanol; C4H10O; [71-36-3]  NIST Chemistry WebBook for detail
   (2) Nitromethane; CH3NO2; [75-52-5]  NIST Chemistry WebBook for detail

Original Measurements:
   Mel'nikova, I.K.; Dissertation, Voronezh University, 1966; Zhuravlev, E.F.; Mel'nikova, I.K., Zh. Fiz. Khim. 41, 1580-4 (1967).

   Temperature = 275 K to 291 K

Prepared By:
   V. P. Sazonov

Experimental Data:   (Notes on the Nomenclature)
Mutual solubility of nitromethane and 1-butanol
t/°CT/K102 * Mass Fraction w1Mole Fraction x1 (compiler)Comment(s)
2.0275.2--Alcohol-rich phase
2.0275.287.90.898Nitromethane-rich phase
6.0279.220.00.233Alcohol-rich phase
6.0279.2--Nitromethane-rich phase
6.3279.5--Alcohol-rich phase
6.3279.585.00.873Nitromethane-rich phase
11.0284.2--Alcohol-rich phase
11.0284.280.40.833Nitromethane-rich phase
14.0287.230.00.342Alcohol-rich phase
14.0287.2--Nitromethane-rich phase
15.5288.7--Alcohol-rich phase
15.5288.771.30.751Nitromethane-rich phase
16.8290.040.00.447Alcohol-rich phase
16.8290.0--Nitromethane-rich phase
17.0290.2--Alcohol-rich phase
17.0290.261.20.657Nitromethane-rich phase
17.3290.552.50.573Alcohol-rich phase
17.3290.5--Nitromethane-rich phase
17.3290.553.00.578Alcohol-rich phase
17.3290.553.00.578 (UCST)Nitromethane-rich phase
   The synthetic method1 was used. No further details were reported.

Source and Purity of Materials:
   (1) Source not specified; pure grade reagent; distilled; b. p = 101.3 °C at 101.33 kPa, n(20 °C, D) = 1.3820, d(20 °C) = 1132 g·L-1.
   (2) Source not specified; pure grade reagent; distilled.

Estimated Errors:
   Solubility: Not reported.
   Temperature: Not reported.
   Pressure: Not reported.

   1 V. F. Alekseev, Zh. Russ. Fiz.-Khim. O-va 8, 249 (1876).