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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Nitromethane with 1-Pentanol
Components:
(1) 1-Pentanol; C5H12O; [71-41-0]
NIST Chemistry WebBook
for detail
(2) Nitromethane; CH3NO2; [75-52-5]
NIST Chemistry WebBook
for detail
Original Measurements:
Mel'nikova, I.K.; Zhuravlev, E.F., Zh. Fiz. Khim. 39, 664-71 (1965); Mel'nikova, I.K., Dissertation, Voronezh University, 1966.
Variables:
Temperature = 282 K to 298 K
Prepared By:
V. P. Sazonov
Experimental Data:
(Notes on the Nomenclature)
Mutual solubility of nitromethane and 1-pentanol
t/°C
T/K
10
2
* Mass Fraction w
1
Mole Fraction x
1
(compiler)
Comment(s)
9.0
282.2
17.0
0.228
Alcohol-rich phase
9.0
282.2
-
-
Nitromethane-rich phase
12.0
285.2
-
-
Alcohol-rich phase
12.0
285.2
85.9
0.898
Nitromethane-rich phase
13.9
287.1
20.7
0.274
Alcohol-rich phase
13.9
287.1
-
-
Nitromethane-rich phase
15.1
288.3
-
-
Alcohol-rich phase
15.1
288.3
84.0
0.883
Nitromethane-rich phase
18.1
291.3
24.8
0.323
Alcohol-rich phase
18.1
291.3
-
-
Nitromethane-rich phase
18.3
291.5
-
-
Alcohol-rich phase
18.3
291.5
81.3
0.863
Nitromethane-rich phase
21.3
294.5
30.3
0.386
Alcohol-rich phase
21.3
294.5
-
-
Nitromethane-rich phase
22.0
295.2
-
-
Alcohol-rich phase
22.0
295.2
76.0
0.821
Nitromethane-rich phase
23.0
296.2
34.6
0.433
Alcohol-rich phase
23.0
296.2
-
-
Nitromethane-rich phase
24.3
297.5
42.6
0.517
Alcohol-rich phase
24.3
297.5
-
-
Nitromethane-rich phase
24.5
297.7
-
-
Alcohol-rich phase
24.5
297.7
67.0
0.746
Nitromethane-rich phase
24.8
298.0
47.2
0.564
Alcohol-rich phase
24.8
298.0
-
-
Nitromethane-rich phase
25.0
298.2
-
-
Alcohol-rich phase
25.0
298.2
57.7
0.663
Nitromethane-rich phase
25.0
298.2
54.0
0.629
Alcohol-rich phase
25.0
298.2
54.0
0.629 (UCST)
Nitromethane-rich phase
Method/Apparatus/Procedure:
The synthetic method
1
was used. No further details were reported.
Source and Purity of Materials:
(1) Source not specified; pure grade reagent; distilled.
(2) Source not specified; pure grade reagent; distilled.
Estimated Errors:
Solubility: Not reported.
Temperature: Not reported.
Pressure: Not reported.
References:
1
V. F. Alekseev, Zh. Russ. Fiz.-Khim. O-va 8, 249 (1876).