IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Nitromethane with 1-Pentanol

   (1) 1-Pentanol; C5H12O; [71-41-0]  NIST Chemistry WebBook for detail
   (2) Nitromethane; CH3NO2; [75-52-5]  NIST Chemistry WebBook for detail

Original Measurements:
   Zhuravleva, I.K.; Zhuravlev, E.F.; Lomakina, N.G., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 18, 499 (1975); *Deposited Doc., VINITI 1566 (1974).

   Temperature = 276 K to 299 K

Prepared By:
   V. P. Sazonov

Experimental Data:   (Notes on the Nomenclature)
Mutual solubility of nitromethane and 1-pentanol
t/°CT/K102 * Mass Fraction w1Mole Fraction x1 (compiler)Comment(s)
3.0276.213.00.178Alcohol-rich phase
3.0276.2--Nitromethane-rich phase
5.0278.213.20.180Alcohol-rich phase
5.0278.2--Nitromethane-rich phase
6.5279.713.60.185Alcohol-rich phase
6.5279.7--Nitromethane-rich phase
7.5280.7--Alcohol-rich phase
7.5280.790.00.929Nitromethane-rich phase
8.5281.714.40.195Alcohol-rich phase
8.5281.7--Nitromethane-rich phase
10.0283.215.10.204Alcohol-rich phase
10.0283.2--Nitromethane-rich phase
11.0284.2--Alcohol-rich phase
11.0284.288.40.917Nitromethane-rich phase
13.0286.2--Alcohol-rich phase
13.0286.287.30.908Nitromethane-rich phase
14.0287.218.40.246Alcohol-rich phase
14.0287.2--Nitromethane-rich phase
14.5287.7--Alcohol-rich phase
14.5287.786.70.904Nitromethane-rich phase
16.0289.2--Alcohol-rich phase
16.0289.285.70.896Nitromethane-rich phase
17.0290.2--Alcohol-rich phase
17.0290.285.10.892Nitromethane-rich phase
18.0291.222.30.293Alcohol-rich phase
18.0291.284.10.884Nitromethane-rich phase
20.0293.2--Alcohol-rich phase
20.0293.282.40.871Nitromethane-rich phase
20.5293.725.70.333Alcohol-rich phase
20.5293.7--Nitromethane-rich phase
21.0294.2--Alcohol-rich phase
21.0294.279.00.844Nitromethane-rich phase
23.5296.730.00.382Alcohol-rich phase
23.5296.776.00.821Nitromethane-rich phase
24.5297.734.70.434Alcohol-rich phase
24.5297.7--Nitromethane-rich phase
25.0298.2--Alcohol-rich phase
25.0298.270.00.771Nitromethane-rich phase
26.0299.240.00.491Alcohol-rich phase
26.0299.260.00.684Nitromethane-rich phase
26.0299.242.10.512Alcohol-rich phase
26.0299.2--Nitromethane-rich phase
26.0299.245.00.542Alcohol-rich phase
26.0299.2--Nitromethane-rich phase
26.0299.250.00.591Alcohol-rich phase
26.0299.2--Nitromethane-rich phase
26.0299.253.50.624Alcohol-rich phase
26.0299.253.50.624 (UCST)Nitromethane-rich phase
   The synthetic method1 was used. No further details were reported.

Source and Purity of Materials:
   (1) Source not specified; purity not specified; distilled; b. p. = 101.3 °C, n(20 °C, D) = 1.3820, d(20 °C) = 1132.0 g·L-1.
   (2) Source not specified; purity not specified; distilled; b. p. = 138 °C, n(20 °C, D) = 1.4100, d(20 °C) = 814.4 g·L−1.

Estimated Errors:
   Solubility: Not reported.
   Temperature: Not reported.
   Pressure: Not reported.

   1 V. F. Alekseev, Zh. Russ. Fiz.-Khim. O-va 8, 249 (1876).