IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Nitromethane with 1-Hexanol
Components:
   (1) Nitromethane; CH3NO2; [75-52-5]  NIST Chemistry WebBook for detail
   (2) 1-Hexanol; C6H14O; [111-27-3]  NIST Chemistry WebBook for detail
Original Measurements:
   Sazonov, V.P.; Filippov, V.V., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 18, 222-5(1975).

 Variables:
   Temperature = 293 K to 309 K

 Prepared By:
   N. V. Sazonov and V. P. Sazonov

 Experimental Data:   (Notes on the Nomenclature)
  
Mutual solubility of nitromethane and 1-hexanol
t/°CT/K102 * Mass Fraction w1Mole Fraction x1 (compiler)Comment(s)
20.00293.1515.000.2280Alcohol-rich phase
20.00293.1588.900.9306Nitromethane-rich phase
24.83297.9820.030.2954Alcohol-rich phase
24.83297.98--Nitromethane-rich phase
30.40303.5524.910.3570Alcohol-rich phase
30.40303.55--Nitromethane-rich phase
30.63303.78--Alcohol-rich phase
30.63303.7879.990.8700Nitromethane-rich phase
32.25305.4031.140.4308Alcohol-rich phase
32.25305.40--Nitromethane-rich phase
33.60306.75--Alcohol-rich phase
33.60306.7574.380.8294Nitromethane-rich phase
33.87307.0234.630.4700Alcohol-rich phase
33.87307.02--Nitromethane-rich phase
34.54307.6940.000.5274Alcohol-rich phase
34.54307.69--Nitromethane-rich phase
34.84307.99--Alcohol-rich phase
34.84307.9969.020.7886Nitromethane-rich phase
35.25308.4044.840.5764Alcohol-rich phase
35.25308.40--Nitromethane-rich phase
35.36308.51--Alcohol-rich phase
35.36308.5164.780.7548Nitromethane-rich phase
35.45308.6049.990.6259Alcohol-rich phase
35.45308.60--Nitromethane-rich phase
35.48308.63--Alcohol-rich phase
35.48308.6360.250.7173Nitromethane-rich phase
35.50308.6552.430.6485Alcohol-rich phase
35.50308.65--Nitromethane-rich phase
35.50308.6555.260.6740Alcohol-rich phase
35.50308.6555.260.6740 (UCST)Nitromethane-rich phase
 Method/Apparatus/Procedure:
   The synthetic method of Alekseev was used. Close to the phase transition temperature heating and cooling of mixture were accomplished in steps at a rate of 0.02 K·h-1.

 Source and Purity of Materials:
   (1) Source not specified; pure grade reagent; distilled through a column of 15 theoretical plates; n(20 °C, D) = 1.3819, d(20 °C) = 1138.1 g·L-1.
   (2) Source not specified; pure grade reagent; distilled through a glass-packed fractionating column; n(20 °C, D) = 1.4182, d(20 °C) = 819.7 g·L-1.

 Estimated Errors:
   Solubility: Not reported.
   Temperature: Not reported.
   Pressure: Not reported.