IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Nitromethane with 1-Hexanol

   (1) Nitromethane; CH3NO2; [75-52-5]  NIST Chemistry WebBook for detail
   (2) 1-Hexanol; C6H14O; [111-27-3]  NIST Chemistry WebBook for detail

Original Measurements:
   Zhuravleva, I.K.; Zhuravlev, E.F.; Rudakova, N.A., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 18, 333 (1975); Deposited Doc., VINITI 1587 (1974).

   Temperature = 283 K to 309 K

Prepared By:
   V. P. Sazonov

Experimental Data:   (Notes on the Nomenclature)
Mutual solubility of nitromethane and 1-hexanol
t/°CT/K102 * Mass Fraction w1Mole Fraction x1 (compiler)Comment(s)
9.5282.711.00.171Alcohol-rich phase
9.5282.7--Nitromethane-rich phase
15.5288.713.50.207Alcohol-rich phase
15.5288.7--Nitromethane-rich phase
16.0289.2--Alcohol-rich phase
16.0289.289.30.933Nitromethane-rich phase
20.0293.216.60.250Alcohol-rich phase
20.0293.2--Nitromethane-rich phase
24.0297.219.30.286Alcohol-rich phase
24.0297.2--Nitromethane-rich phase
26.5299.721.30.312Alcohol-rich phase
26.5299.7--Nitromethane-rich phase
29.0302.224.30.350Alcohol-rich phase
29.0302.2--Nitromethane-rich phase
30.0303.2--Alcohol-rich phase
30.0303.279.90.869Nitromethane-rich phase
30.5303.726.60.378Alcohol-rich phase
30.5303.7--Nitromethane-rich phase
32.5305.730.50.424Alcohol-rich phase
32.5305.7--Nitromethane-rich phase
33.0306.232.50.446Alcohol-rich phase
33.0306.2--Nitromethane-rich phase
34.0307.236.00.485Alcohol-rich phase
34.0307.2--Nitromethane-rich phase
35.0308.238.50.512Alcohol-rich phase
35.0308.2--Nitromethane-rich phase
35.0308.241.40.542Alcohol-rich phase
35.0308.2--Nitromethane-rich phase
35.0308.245.20.580Alcohol-rich phase
35.0308.2--Nitromethane-rich phase
35.0308.249.40.620Alcohol-rich phase
35.0308.2--Nitromethane-rich phase
36.0309.2--Alcohol-rich phase
36.0309.269.10.789Nitromethane-rich phase
36.0309.2--Alcohol-rich phase
36.0309.259.90.714Nitromethane-rich phase
35.6308.852.50.649Alcohol-rich phase
35.6308.852.50.649 (UCST)Nitromethane-rich phase
   The synthetic method1 was used. No further details were reported.

Source and Purity of Materials:
   (1) Source not specified; purity not specified; distilled; b.p. = 101.3 °C, n(20 °C,D) = 1.3820, d(20 °C) = 1132.0 g·L−1.
   (2) Source not specified; purity not specified; distilled; b.p. = 157.2 °C, n(20 °C,D) = 1.4190, d(20 °C) = 818.6 g·L−1.

Estimated Errors:
   Solubility: Not reported.
   Temperature: Not reported.
   Pressure: Not reported.

   1 V. F. Alekseev, Zh. Russ. Fiz.-Khim. O-va 8, 249 (1876).