IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Nitromethane with 1-Octanol

   (1) Nitromethane; CH3NO2; [75-52-5]  NIST Chemistry WebBook for detail
   (2) 1-Octanol; C8H18O; [111-87-5]  NIST Chemistry WebBook for detail

Original Measurements:
   Zhuravleva, I.K.; Zhuravlev, E.F.; Lomakina, N.G., Zh. Fiz. Khim. 51, 1700-7 (1977).

   Temperature = 298 K to 322 K

Prepared By:
   V. P. Sazonov

Experimental Data:   (Notes on the Nomenclature)
Mutual solubility of nitromethane and 1-octanol
t/°CT/K102 * Mass Fraction w1Mole Fraction x1 (compiler)Comment(s)
24.5297.710.00.192Alcohol-rich phase
24.5297.7--Nitromethane-rich phase
30.5303.7--Alcohol-rich phase
30.5303.790.00.950Nitromethane-rich phase
40.0313.220.00.348Alcohol-rich phase
40.0313.2--Nitromethane-rich phase
43.5316.7--Alcohol-rich phase
43.5316.780.00.895Nitromethane-rich phase
46.0319.230.00.478Alcohol-rich phase
46.0319.2--Nitromethane-rich phase
48.0321.240.00.587Alcohol-rich phase
48.0321.270.00.833Nitromethane-rich phase
48.5321.7--Alcohol-rich phase
48.5321.760.00.762Nitromethane-rich phase
49.0322.251.00.690Alcohol-rich phase
49.0322.2--Nitromethane-rich phase
49.0322.2--Alcohol-rich phase
49.0322.2-- (UCST)Nitromethane-rich phase
   The synthetic method1 was used. No further details were reported.

Source and Purity of Materials:
   (1) Source not specified; purity not specified; n(20 °C, D) = 1.3820, d(20 °C) = 1133.0a g·L-1.
   (2) Source not specified; purity not specified; n(20 °C, D) = 1.4395, d(20 °C) = 824 g·L-1.
aRecorded as 1330.0 in original. Value corrected by compiler.

Estimated Errors:
   Solubility: Not reported.
   Temperature: Not reported.
   Pressure: Not reported.

   1 V. F. Alekseev, Zh. Russ. Fiz.-Khim. O-va 8, 249 (1876).