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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Nitromethane with 1-Octanol
Components:
(1) Nitromethane; CH3NO2; [75-52-5]
NIST Chemistry WebBook
for detail
(2) 1-Octanol; C8H18O; [111-87-5]
NIST Chemistry WebBook
for detail
Original Measurements:
Dewan, R.K.; Menta, S.K., J. Chem. Thermodyn. 18, 101-6 (1986).
Variables:
Temperature = 303 K
Prepared By:
V. P. Sazonov
Experimental Remarks:
The mole fraction of nitromethane in the (2)-rich phase at 303.15 K (30.00 °C, compiler) was reported to be x
1
= 0.2500, corresponding to 100 w
1
= 13.51 (compiler).
The mole fraction of nitromethane in the (1)-rich phase at 303.15 K (30.00 °C, compiler) was reported to be x
1
= 0.9450, corresponding to 100 w
1
= 88.95 (compiler).
Experimental Data:
(Notes on the Nomenclature)
Method/Apparatus/Procedure:
Excess volumes of 1-octanol and nitro-methane were measured using a continuous-dilution dilatometer. No further details were reported.
Source and Purity of Materials:
(1) J. T. Baker Chemicals; fractionally distilled;
d
(30 °C) = 1123.5 g·L
-1
.
(2) Fluka AG Buchs; fractionally distilled;
d
(30 °C) = 818.7 g·L
-1
.
Estimated Errors:
Solubility: Not reported.
Temperature: Not reported.
Pressure: Not reported.