Home
Introduction
Search Menu
IUPAC Series (PDF)
Reference
Version History
About the Project
Disclaimer
Contact Us
Acknowledgements
IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Nitromethane with 1-Decanol
Components:
(1) Nitromethane; CH3NO2; [75-52-5]
NIST Chemistry WebBook
for detail
(2) 1-Decanol; C10H22O; [112-30-1]
NIST Chemistry WebBook
for detail
Original Measurements:
Francis, A.W., J. Phys. Chem. 60, 20-7 (1956).
Variables:
Temperature = 273 K to 330 K
Prepared By:
V. P. Sazonov
Experimental Data:
(Notes on the Nomenclature)
Mutual solubility of nitromethane and 1-decanol
t/°C
T/K
10
2
* Mass Fraction w
1
Mole Fraction x
1
(compiler)
Comment(s)
0.0
273.2
-
-
Alcohol-rich phase
0.0
273.2
98.0
0.992
Nitromethane-rich phase
10.0
283.2
7.0
0.164
Alcohol-rich phase
10.0
283.2
96.0
0.984
Nitromethane-rich phase
20.0
293.2
7.0
0.164
Alcohol-rich phase
20.0
293.2
95.0
0.980
Nitromethane-rich phase
23.4
296.6
7.5
0.174
Alcohol-rich phase
23.4
296.6
94.5
0.978
Nitromethane-rich phase
26.0
299.2
8.0
0.184
Alcohol-rich phase
26.0
299.2
94.0
0.976
Nitromethane-rich phase
56.3
329.5
54.0
0.753
Alcohol-rich phase
56.3
329.5
54.0
0.753 (UCST)
Nitromethane-rich phase
Method/Apparatus/Procedure:
Observations were made after vigorous shaking in glass-stoppered graduated tubes of 15 mL capacity, immersed in water baths in large Dewar flasks. The water was agitated with a rapid stream of air bubbles. The temperature was adjusted by adding cooler or warmer water occasionally.
Source and Purity of Materials:
(1) Eastman Kodak Co.; distilled through a 30 cm column; b. p. = 101.25 °C, m. p. = -30.5 °C,
n
(20 °C, D) = 1.3820,
d
(25 °C) = 1129.8 g·L
-1
.
(2) Source not specified; purified by crystallization; m. p. = 6.8 °C,
n
(20 °C, D) = 1.4372,
d
(20 °C) = 831.8 g·L
-1
.
Estimated Errors:
Solubility: Not reported.
Temperature: Not reported.
Pressure: Not reported.