IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Nitromethane with 1-Decanol

   (1) Nitromethane; CH3NO2; [75-52-5]  NIST Chemistry WebBook for detail
   (2) 1-Decanol; C10H22O; [112-30-1]  NIST Chemistry WebBook for detail

Original Measurements:
   Francis, A.W., J. Phys. Chem. 60, 20-7 (1956).

   Temperature = 273 K to 330 K

Prepared By:
   V. P. Sazonov

Experimental Data:   (Notes on the Nomenclature)
Mutual solubility of nitromethane and 1-decanol
t/°CT/K102 * Mass Fraction w1Mole Fraction x1 (compiler)Comment(s)
0.0273.2--Alcohol-rich phase
0.0273.298.00.992Nitromethane-rich phase
10.0283.27.00.164Alcohol-rich phase
10.0283.296.00.984Nitromethane-rich phase
20.0293.27.00.164Alcohol-rich phase
20.0293.295.00.980Nitromethane-rich phase
23.4296.67.50.174Alcohol-rich phase
23.4296.694.50.978Nitromethane-rich phase
26.0299.28.00.184Alcohol-rich phase
26.0299.294.00.976Nitromethane-rich phase
56.3329.554.00.753Alcohol-rich phase
56.3329.554.00.753 (UCST)Nitromethane-rich phase
   Observations were made after vigorous shaking in glass-stoppered graduated tubes of 15 mL capacity, immersed in water baths in large Dewar flasks. The water was agitated with a rapid stream of air bubbles. The temperature was adjusted by adding cooler or warmer water occasionally.

Source and Purity of Materials:
   (1) Eastman Kodak Co.; distilled through a 30 cm column; b. p. = 101.25 °C, m. p. = -30.5 °C, n(20 °C, D) = 1.3820, d(25 °C) = 1129.8 g·L-1.
   (2) Source not specified; purified by crystallization; m. p. = 6.8 °C, n(20 °C, D) = 1.4372, d(20 °C) = 831.8 g·L-1.

Estimated Errors:
   Solubility: Not reported.
   Temperature: Not reported.
   Pressure: Not reported.