IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Nitromethane with 1-Dodecanol

   (1) Nitromethane; CH3NO2; [75-52-5]  NIST Chemistry WebBook for detail
   (2) 1-Dodecanol; C12H26O; [112-53-8]  NIST Chemistry WebBook for detail

Original Measurements:
   Francis, A.W., J. Phys. Chem. 60, 20-7 (1956).

   Temperature = 289 K to 336 K

Prepared By:
   V. P. Sazonov

Experimental Data:   (Notes on the Nomenclature)
Mutual solubility of nitromethane and 1-dodecanol
t/°CT/K102 * Mass Fraction w1Mole Fraction x1 (compiler)Comment(s)
16.0289.2--Alcohol-rich phase
16.0289.298.00.993Nitromethane-rich phase
22.0295.23.00.09Alcohol-rich phase
22.0295.297.00.990Nitromethane-rich phase
28.0301.27.00.19Alcohol-rich phase
28.0301.296.00.987Nitromethane-rich phase
29.0302.28.00.21Alcohol-rich phase
29.0302.296.00.987Nitromethane-rich phase
63.0336.253.00.78Alcohol-rich phase
63.0336.253.00.78 (UCST)Nitromethane-rich phase
   Observations were made after vigorous shaking in glass-stoppered graduated tubes of 15 mL capacity, immersed in water baths in large Dewar flasks. The water was agitated with a rapid stream of air bubbles. The temperature was adjusted by adding cooler or warmer water occasionally.

Source and Purity of Materials:
   (1) Eastman Kodak Co.; distilled through a 30 cm column; b. p. = 101.25 °C, m. p. = -30.5 °C, n(20 °C, D) = 1.3820, d(25 °C) = 1129.8 g·L-1.
   (2) Source not specified; purified by crystallization; m. p. = 22.7 °C, n(20 °C, D) = 1.4410, d(24 °C) = 832 g·L−1.

Estimated Errors:
   Solubility: Not reported.
   Temperature: Not reported.
   Pressure: Not reported.