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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Nitromethane with 1-Dodecanol
Components:
(1) Nitromethane; CH3NO2; [75-52-5]
NIST Chemistry WebBook
for detail
(2) 1-Dodecanol; C12H26O; [112-53-8]
NIST Chemistry WebBook
for detail
Original Measurements:
Zhuravleva, I.K.; Zhuravlev, E.F.; Islamova, R.S., Zh. Fiz. Khim. 48, 1863 (1974). *Deposited Doc., VINITI 873 (1974).
Variables:
Temperature = 296 K to 340 K
Prepared By:
V. P. Sazonov
Experimental Data:
(Notes on the Nomenclature)
Mutual solubility of nitromethane and 1-dodecanol
t/°C
T/K
10
2
* Mass Fraction w
1
Mole Fraction x
1
(compiler)
Comment(s)
22.4
295.6
-
-
Alcohol-rich phase
22.4
295.6
98.0
0.993
Nitromethane-rich phase
33.0
306.2
9.0
0.232
Alcohol-rich phase
33.0
306.2
-
-
Nitromethane-rich phase
39.0
312.2
-
-
Alcohol-rich phase
39.0
312.2
94.8
0.982
Nitromethane-rich phase
48.0
321.2
-
-
Alcohol-rich phase
48.0
321.2
92.0
0.972
Nitromethane-rich phase
49.2
322.4
17.0
0.383
Alcohol-rich phase
49.2
322.4
-
-
Nitromethane-rich phase
57.8
330.0
-
-
Alcohol-rich phase
57.8
330.0
87.3
0.955
Nitromethane-rich phase
58.4
331.6
24.5
0.498
Alcohol-rich phase
58.4
331.6
-
-
Nitromethane-rich phase
62.0
335.2
30.0
0.567
Alcohol-rich phase
62.0
335.2
-
-
Nitromethane-rich phase
63.7
336.9
-
-
Alcohol-rich phase
63.7
336.9
79.6
0.923
Nitromethane-rich phase
64.7
337.9
38.0
0.652
Alcohol-rich phase
64.7
337.9
-
-
Nitromethane-rich phase
66.0
339.2
-
-
Alcohol-rich phase
66.0
339.2
73.2
0.893
Nitromethane-rich phase
66.4
339.6
50.2
0.755
Alcohol-rich phase
66.4
339.6
-
-
Nitromethane-rich phase
66.8
340.0
57.4
0.804
Alcohol-rich phase
66.8
340.0
67.0
0.861
Nitromethane-rich phase
66.8
340.0
58.0
0.808
Alcohol-rich phase
66.8
340.0
58.0
0.808 (UCST)
Nitromethane-rich phase
Method/Apparatus/Procedure:
The synthetic method
1
was used. No further details were reported.
Source and Purity of Materials:
(1) Source not specified; pure grade reagent; freshly distilled.
(2) Source not specified; pure grade reagent; freshly distilled.
Estimated Errors:
Solubility: Not reported.
Temperature: Not reported.
Pressure: Not reported.
References:
1
V. F. Alekseev, Zh. Russ. Fiz.-Khim. O-va 8, 249 (1876).