IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Nitromethane with 1-Dodecanol

Components:
   (1) Nitromethane; CH3NO2; [75-52-5]  NIST Chemistry WebBook for detail
   (2) 1-Dodecanol; C12H26O; [112-53-8]  NIST Chemistry WebBook for detail

Original Measurements:
   Zhuravleva, I.K.; Zhuravlev, E.F.; Islamova, R.S., Zh. Fiz. Khim. 48, 1863 (1974). *Deposited Doc., VINITI 873 (1974).

Variables:
   Temperature = 296 K to 340 K

Prepared By:
   V. P. Sazonov

Experimental Data:   (Notes on the Nomenclature)
  
Mutual solubility of nitromethane and 1-dodecanol
t/°CT/K102 * Mass Fraction w1Mole Fraction x1 (compiler)Comment(s)
22.4295.6--Alcohol-rich phase
22.4295.698.00.993Nitromethane-rich phase
33.0306.29.00.232Alcohol-rich phase
33.0306.2--Nitromethane-rich phase
39.0312.2--Alcohol-rich phase
39.0312.294.80.982Nitromethane-rich phase
48.0321.2--Alcohol-rich phase
48.0321.292.00.972Nitromethane-rich phase
49.2322.417.00.383Alcohol-rich phase
49.2322.4--Nitromethane-rich phase
57.8330.0--Alcohol-rich phase
57.8330.087.30.955Nitromethane-rich phase
58.4331.624.50.498Alcohol-rich phase
58.4331.6--Nitromethane-rich phase
62.0335.230.00.567Alcohol-rich phase
62.0335.2--Nitromethane-rich phase
63.7336.9--Alcohol-rich phase
63.7336.979.60.923Nitromethane-rich phase
64.7337.938.00.652Alcohol-rich phase
64.7337.9--Nitromethane-rich phase
66.0339.2--Alcohol-rich phase
66.0339.273.20.893Nitromethane-rich phase
66.4339.650.20.755Alcohol-rich phase
66.4339.6--Nitromethane-rich phase
66.8340.057.40.804Alcohol-rich phase
66.8340.067.00.861Nitromethane-rich phase
66.8340.058.00.808Alcohol-rich phase
66.8340.058.00.808 (UCST)Nitromethane-rich phase
Method/Apparatus/Procedure:
   The synthetic method1 was used. No further details were reported.

Source and Purity of Materials:
   (1) Source not specified; pure grade reagent; freshly distilled.
   (2) Source not specified; pure grade reagent; freshly distilled.

Estimated Errors:
   Solubility: Not reported.
   Temperature: Not reported.
   Pressure: Not reported.

References:
   1 V. F. Alekseev, Zh. Russ. Fiz.-Khim. O-va 8, 249 (1876).