IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Nitromethane with 1-Tridecanol

   (1) Nitromethane; CH3NO2; [75-52-5]  NIST Chemistry WebBook for detail
   (2) 1-Tridecanol; C13H28O; [112-70-9]  NIST Chemistry WebBook for detail

Original Measurements:
   Zhuravleva, I.K.; Zhuravlev, E.F.; Mukhametshina, V.B.; Khisametdinova, Z Z., Zh. Obshch. Khim. 47, 1686-90 (1977).

   Temperature = 303 K to 345 K

Prepared By:
   V. P. Sazonov

Experimental Remarks:

   The mutual solubilities of nitromethane and 1-tridecanol in mass percent over the specified temperature range were presented in graphical form in the original publication. The numerical data, in the table below, were provided by the authors at the request of the compiler.

Monotectic equilibrium is realized at 28.0 °C (301.2 K, compiler).

Experimental Data:   (Notes on the Nomenclature)

Mutual solubility of nitromethane and 1-tridecanol
t/°CT/KMass Fraction w1 (compiler) Mole Fraction x1 (compiler)Comment(s)
303037.4 x 1020.208Alcohol-rich phase
3030398.0 x 1020.994Nitromethane-rich phase
4031310.3 x 1020.274Alcohol-rich phase
4031396.5 x 1020.989Nitromethane-rich phase
4531812.4 x 1020.317Alcohol-rich phase
4531895.1 x 1020.985Nitromethane-rich phase
5032314.6 x 1020.360Alcohol-rich phase
5032393.4 x 1020.979Nitromethane-rich phase
5532817.4 x 1020.409Alcohol-rich phase
5532891.6 x 1020.973Nitromethane-rich phase
71.5344.756.0 x 1020.807Alcohol-rich phase
71.5344.756.0 x 1020.807 (UCST)Nitromethane-rich phase
   The synthetic method1 was used. No further details were reported.

Source and Purity of Materials:
   (1) Source not specified; pure grade reagent; distilled; b. p. = 101.3 °C, n(20 °C, D) = 1.3820,d(20 °C) = 1132 g·L-1.
   (2) Source not specified; pure grade reagent; distilled; b. p. = 117.3 °C/67 Pa, m. p = 30.5 °C, d(34 °C) = 822.3 g·L-1.

Estimated Errors:
   Solubility: Not reported.
   Temperature: Not reported.
   Pressure: Not reported.

   1 V. F. Alekseev, Zh. Russ. Fiz.-Khim. O-va 8, 249 (1876).