IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Nitromethane with 1-Tridecanol
Components:
   (1) Nitromethane; CH3NO2; [75-52-5]  NIST Chemistry WebBook for detail
   (2) 1-Tridecanol; C13H28O; [112-70-9]  NIST Chemistry WebBook for detail
Original Measurements:
   Zhuravleva, I.K.; Mukhametshin, N.P., Zh. Obshch. Khim. 49, 1217-22 (1979).

 Variables:
   Temperature = 307 K to 343 K

 Prepared By:
   V. P. Sazonov

 Experimental Remarks:
   The mutual solubilities of nitromethane and 1-tridecanol in mass percent over the specified temperature range were presented in graphical form in the original publication. The numeric data, in the table below, were provided by the authors at the request of the compiler.

Monotectic equilibrium is realized at 28.0 °C (301.2 K, compiler).

Experimental Data:   (Notes on the Nomenclature)
  

Mutual solubility of nitromethane and 1-tridecanol
t/°CT/K102 * Mass Fraction w1Mole Fraction x1 (compiler)Comment(s)
33.3306.55.20.153Alcohol-rich phase
33.3306.5--Nitromethane-rich phase
37.7310.96.10.176Alcohol-rich phase
37.7310.9--Nitromethane-rich phase
39.1312.3--Alcohol-rich phase
39.1312.394.60.983Nitromethane-rich phase
45.4318.6--Alcohol-rich phase
45.4318.693.30.979Nitromethane-rich phase
49.1322.310.80.284Alcohol-rich phase
49.1322.3--Nitromethane-rich phase
55.4328.615.00.367Alcohol-rich phase
55.4328.6--Nitromethane-rich phase
57.8331.0--Alcohol-rich phase
57.8331.090.00.967Nitromethane-rich phase
61.6334.821.90.479Alcohol-rich phase
61.6334.8--Nitromethane-rich phase
64.2337.424.80.520Alcohol-rich phase
64.2337.4--Nitromethane-rich phase
66.1339.3--Alcohol-rich phase
66.1339.380.00.929Nitromethane-rich phase
66.3339.530.00.585Alcohol-rich phase
66.3339.5--Nitromethane-rich phase
68.3341.5--Alcohol-rich phase
68.3341.570.00.884Nitromethane-rich phase
69.1342.340.00.686Alcohol-rich phase
69.1342.3--Nitromethane-rich phase
69.4342.650.00.766Alcohol-rich phase
69.4342.6--Nitromethane-rich phase
69.5342.7--Alcohol-rich phase
69.5342.760.00.831Nitromethane-rich phase
69.5342.756.80.812Alcohol-rich phase
69.5342.756.80.812 (UCST)Nitromethane-rich phase
 Method/Apparatus/Procedure:
   The synthetic method1 was used. No further details were reported.

 Source and Purity of Materials:
   (1) Source not specified; pure grade reagent; distilled; b. p. = 101.3 °C, n(20 °C, D) = 1.3820, d(20 °C) = 1132 g·L-1.
   (2) Source not specified; pure grade reagent; distilled; b. p. = 117.3 °C/67 Pa, m. p. = 30.5 °C, n(40 °C, D) = 1.4373, d(34 °C) = 822.3 g·L-1.

 Estimated Errors:
   Solubility: Not reported.
   Temperature: Not reported.
   Pressure: Not reported.

 References:
   1 V. F. Alekseev, Zh. Russ. Fiz.-Khim. O-va 8, 249 (1876).