IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Nitromethane with 1-Tridecanol
Components:
   (1) Nitromethane; CH3NO2; [75-52-5]  NIST Chemistry WebBook for detail
   (2) 1-Tridecanol; C13H28O; [112-70-9]  NIST Chemistry WebBook for detail
Original Measurements:
   Zhuravleva, I.K.; Yamshanova, N.M., Termicheskij analiz i phazovye ravnovesiya, Perm, 1985, pp. 109-15.

 Variables:
   Temperature = 304 K to 345 K

 Prepared By:
   V. P. Sazonov

 Experimental Data:   (Notes on the Nomenclature)
  
Mutual solubility of nitromethane and 1-tridecanol
t/°CT/K102 * Mass Fraction w1Mole Fraction x1 (compiler)Comment(s)
30.9304.16.10.175Alcohol-rich phase
30.9304.1--Nitromethane-rich phase
36.4309.68.00.219Alcohol-rich phase
36.4309.6--Nitromethane-rich phase
38.2311.48.20.226Alcohol-rich phase
38.2311.4--Nitromethane-rich phase
45.8319.0--Alcohol-rich phase
45.8319.094.80.984Nitromethane-rich phase
51.6324.815.60.376Alcohol-rich phase
51.6324.8--Nitromethane-rich phase
54.8328.0--Alcohol-rich phase
54.8328.092.40.975Nitromethane-rich phase
58.8332.019.60.443Alcohol-rich phase
58.8332.0--Nitromethane-rich phase
61.3334.5--Alcohol-rich phase
61.3334.586.90.956Nitromethane-rich phase
62.4335.623.30.498Alcohol-rich phase
62.4335.6--Nitromethane-rich phase
66.4339.629.80.581Alcohol-rich phase
66.4339.6--Nitromethane-rich phase
67.1340.3--Alcohol-rich phase
67.1340.382.80.940Nitromethane-rich phase
68.6341.834.40.631Alcohol-rich phase
68.6341.8--Nitromethane-rich phase
69.6342.8--Alcohol-rich phase
69.6342.875.40.909Nitromethane-rich phase
70.9344.143.90.719Alcohol-rich phase
70.9344.1--Nitromethane-rich phase
71.1344.3--Alcohol-rich phase
71.1344.369.20.880Nitromethane-rich phase
71.2344.4--Alcohol-rich phase
71.2344.460.50.833Nitromethane-rich phase
71.3344.554.40.796Alcohol-rich phase
71.3344.554.40.796 (UCST)Nitromethane-rich phase
 Method/Apparatus/Procedure:
   Solubility temperatures of the liquid phases were determined by the synthetic method.1 No further experimental details given.

 Source and Purity of Materials:
   (1) Source not specified; pure grade reagent; purified; n(20 °C, D) = 1.3820, d(20 °C) = 1132.0 g·L­1.
   (2) Source not specified; purified; n(40 °C, D) = 1.4373, d(40 °C) = 822.3 g·L-1.

 Estimated Errors:
   Solubility: Not reported.
   Temperature: Not reported.
   Pressure: Not reported.

 References:
   1 V. F. Alekseev, Zh. Russ. Fiz.-Khim. O-va 8, 249 (1876).