IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Nitromethane with 1-Pentadecanol

   (1) 1-Pentadecanol; C15H32O; [629-76-5]  NIST Chemistry WebBook for detail
   (2) Nitromethane; CH3NO2; [75-52-5]  NIST Chemistry WebBook for detail

Original Measurements:
   Zhuravleva, I.K.; Zhuravlev, E.F.; Mukhametshina, V.B.; Khisametdinova, Z.Z., Zh. Fiz. Khim. 51, 1003 (1977); *Deposited Doc., VINITI 4286 (1976).

   Temperature = 312 K to 353 K

Prepared By:
   V. P. Sazonov

Experimental Remarks:


Monotectic equilibrium is realized at 38.5 °C (311.7 K, compiler).

Experimental Data:   (Notes on the Nomenclature)

Solubility of nitromethane and 1-pentadecanol
t/°CT/K102 * Mass Fraction w1Mole Fraction x1 (compiler)Comment(s)
39.0 a312.26.50.206Alcohol-rich phase
39.0 a312.2--Nitromethane-rich phase
40.0 a313.24.80.159Alcohol-rich phase
40.0 a313.2--Nitromethane-rich phase
40.5 a313.73.80.129Alcohol-rich phase
40.5 a313.7--Nitromethane-rich phase
41.0 a314.22.50.088Alcohol-rich phase
41.0 a314.2--Nitromethane-rich phase
41.0314.28.00.246Alcohol-rich phase
41.0314.2--Nitromethane-rich phase
42.0 a315.21.00.036Alcohol-rich phase
42.0 a315.2--Nitromethane-rich phase
47.5320.79.50.282Alcohol-rich phase
47.5320.7--Nitromethane-rich phase
55.5328.712.50.384Alcohol-rich phase
55.5328.7--Nitromethane-rich phase
57.0330.2--Alcohol-rich phase
57.0330.295.50.988Nitromethane-rich phase
61.0334.2--Alcohol-rich phase
61.0334.294.60.985Nitromethane-rich phase
66.0339.219.50.475Alcohol-rich phase
66.0339.2--Nitromethane-rich phase
67.5340.721.70.509Alcohol-rich phase
67.5340.7--Nitromethane-rich phase
68.0341.2--Alcohol-rich phase
68.0341.292.50.979Nitromethane-rich phase
70.0343.2--Alcohol-rich phase
70.0343.291.50.976Nitromethane-rich phase
71.0344.225.00.555Alcohol-rich phase
71.0344.2--Nitromethane-rich phase
71.5344.7--Alcohol-rich phase
71.5344.790.50.973Nitromethane-rich phase
72.5345.7--Alcohol-rich phase
72.5345.789.50.970Nitromethane-rich phase
74.0347.230.00.616Alcohol-rich phase
74.0347.287.50.963Nitromethane-rich phase
75.5348.7--Alcohol-rich phase
75.5348.786.00.958Nitromethane-rich phase
76.6349.735.00.668Alcohol-rich phase
76.6349.7--Nitromethane-rich phase
77.0350.2--Alcohol-rich phase
77.0350.283.50.950Nitromethane-rich phase
78.0351.2--Alcohol-rich phase
78.0351.280.50.939Nitromethane-rich phase
78.5351.742.50.734Alcohol-rich phase
78.5351.777.50.928Nitromethane-rich phase
79.5352.748.50.779Alcohol-rich phase
79.5352.773.00.910Nitromethane-rich phase
79.5352.756.00.826Alcohol-rich phase
79.5352.768.00.888Nitromethane-rich phase
79.5352.7--Alcohol-rich phase
79.5352.763.00.864Nitromethane-rich phase
79.5352.760.00.849Alcohol-rich phase
79.5352.760.00.849 (UCST)Nitromethane-rich phase
   a  Solubility of the solid phase.

   The synthetic method1 was used. No further details were reported.

Source and Purity of Materials:
   (1) Source not specified; pure grade reagent; distilled; b. p. = 101.3 °C/102 kPa, n(20 °C, D) = 1.3820, d(20 °C)
d(20 °C) = 1132.0 g·L-1.
   (2) Source not specified; pure grade reagent; distilled; b. p. = 162 °C/67 Pa, m. p = 43.0 °C, n(50 °C, D) = 1.4390.

Estimated Errors:
   Solubility: Not reported.
   Temperature: Not reported.
   Pressure: Not reported.

   1 V. F. Alekseev, Zh. Russ. Fiz.-Khim. O-va 8, 249 (1876).
   3A. V. Nikolaev, Yu. A. Dyadin, and I. I. Yakovlev, Dokl. Akad. Nauk SSSR 170, 110 (1966).