IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Nitromethane with 1-Alkyl glyceryl ethers
Components:
   (1) 1-Alkyl glyceryl ethers; C13H28O3 - C24H50O3; []  NIST Chemistry WebBook for detail
   (2) Nitromethane; CH3NO2; [75-52-5]  NIST Chemistry WebBook for detail
Original Measurements:
   H.H.O. Schmid; Mangold, H.K.; Lundberg, W.O.; Baumann, W.J., Microchem. J. 11, 306-14 (1966).

 Variables:
   Temperature = 326 K to 369 K

 Prepared By:
   V. P. Sazonov

 Experimental Data:   (Notes on the Nomenclature)
  
Upper critical solution temperatures of the systems nitromethane + alkyl glyceryl ether
t/°CT/KChemical Name
52.5325.71-(cis,cis,cis-9,12,15-Octadecatrienoxy)-2,3-propanediol; C21H38O3;
55.0328.21-Decoxy-2,3-propanediol; C13H28O3; [92219-12-0] 1-Undecoxy-2,3-propanediol; C14H30O3; [126923-57-7]
61.5334.71-Undecoxy-2,3-propanediol; C14H30O3; [126923-57-7]
62.0335.21-(cis,cis-9,12-Octadecadienoxy)-2,3-propanediol; C21H40O3; [70518-62-6]
66.5339.71-Dodecoxy-2,3-propanediol; C15H32O3; [1561-07-5]
68.0341.21-(cis-9-Hexadecenoxy)-2,3-propanediol; C19H38O3;
70.5343.71-Tridecoxy-2,3-propanediol; C16H34O3; [126923-58-8]
74.0347.21-Tetradecoxy-2-3-propanediol; C17H36O3; [92219-13-1]
75.0348.21-(cis-9-Octadecenoxy)-2,3-propanediol; C21H42O3; [2929-07-9]
77.0350.21-(trans-9-Octadecenoxy)-2,3-propanediol; C21H42O3; [593-31-7]
77.5350.71-Pentadecoxy-2,3-propanediol; C18H38O1; [124770-96-3]
81.0354.21-Hexadecoxy-2,3-proanediol; C19H40O3; [506-03-6]
84.0357.21-Heptadecoxy-2,3-propanediol; C20H42O3; [113817-63-3]
87.5360.71-Octadecoxy-2,3-propanediol; C21H44O3; [544-62-7]
90.5363.71-Nonadecoxy-2,3-propanediol; C22H46O3; [10431-03-5]
93.0366.21-Eicosoxy-2,3-propanediol; C23H48O3; [158850-88-5]
95.5368.71-Heneicosoxy-2,3-propanediol; C24H50O3; [158789-24-3]
 Method/Apparatus/Procedure:
   A microscope equipped with a heating stage1 was employed for determining UCST values. No further experimental details are given.

 Source and Purity of Materials:
   (1) Fisher Scientific Co.; certified, No. N-98.
   (2) Synthesized as in Baumann and Mangold.2

 Estimated Errors:
   Solubility: Not specified.
   Temperature: Not specified.
   Pressure: Not specified.

 References:
   1 H. H. O. Schmid, H. K. Mangold, and W. O. Lundberg, J. Am. Oil Chem. Soc. 42, 372 (1965).
   2 W. J. Baumann and H. K. Mangold, J. Org. Chem. 29, 3055 (1964).