IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Nitromethane with 1,2-Dialkyl glyceryl ethers
Components:
   (1) Nitromethane; CH3NO2; [75-52-5]  NIST Chemistry WebBook for detail
   (2) 1,2-Dialkyl glyceryl ethers; C33H68O3 - C41H84O3; []  NIST Chemistry WebBook for detail
Original Measurements:
   H.H.O. Schmid; Mangold, H.K.; Lundberg, W.O.; Baumann, W.J., Microchem. J. 11, 306-14 (1966).

 Variables:
   Temperature = 396 K to 427 K

 Prepared By:
   V. P. Sazonov

 Experimental Data:   (Notes on the Nomenclature)
  
Upper critical solution temperatures of the systems nitromethane + 1,2-dialkyl glyceryl ether
t/°CT/KChemical Name
123.0396.22-(Dodecyloxy)-3-(octadecyloxy)-1-propanol; C33H68O3; [6076-36-4]
126.0399.22,3-Bis(9-octadecenyloxy)-(Z,Z)-1-propanol; C39H76O3; [6076-41-1]
131.5404.73-(Octadecyloxy)-2-(tetradecyloxy)-1-propanol; C35H72O3; [6076-37-5]
132.0405.22,3-Bis(hexadecyloxy)-1-propanol; C35H72O3; [6076-35-3]
136.0409.23-(Octadecyloxy)-2-(cis-9-octadecenyloxy)-1-propanol; C39H78O3
136.5409.73-(cis-9-Octadecenyloxy)-2-(octadecyloxy)-1-propanol; C39H78O3
136.5409.73-(Octadecyloxy)-2-(trans-9-octadecenyloxy)-1-propanol; C39H78O3
139.5412.73-(Hexadecyloxy)-2-(octadecyloxy)-1-propanol; C37H76O3; [6110-57-2]
139.5412.72-(Hexadecyloxy)-3-(octadecyloxy)-1-propanol; C37H76O3; [6110-58-3]
147.0420.22,3-Bis(octadecyloxy)-1-propanol; C39H80O3; [6076-38-6]
154.0427.22-(Eicosyloxy)-3-(octadecyloxy)-1-propanol; C41H84O3; [6068-26-4]
 Method/Apparatus/Procedure:
   A microscope equipped with a heating stage1 was employed for determining UCST values. No further experimental details are given.

 Source and Purity of Materials:
   (1) Fisher Scientific Co.; certified, No. N-98.
   (2) Synthesized as in Baumann and Mangold.2

 Estimated Errors:
   Solubility: Not specified.
   Temperature: Not specified.
   Pressure: Not specified.

 References:
   1 H. H. O. Schmid, H. K. Mangold, and W. O. Lundberg, J. Am. Oil Chem. Soc. 42, 372 (1965).
   2 W. J. Baumann and H. K. Mangold, J. Org. Chem. 29, 3055 (1964).