IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Nitromethane with 1,2,3-Trialkyl glyceryl ethers

   (1) Nitromethane; CH3NO2; [75-52-5]  NIST Chemistry WebBook for detail
   (2) 1,2,3-Trialkyl glyceryl ethers; C47H96O3 - C57H116O3; []  NIST Chemistry WebBook for detail

Original Measurements:
   H.H.O. Schmid; Mangold, H.K.; Lundberg, W.O.; Baumann, W.J., Microchem. J. 11, 306-14 (1966).

   Temperature = 450 K to 469 K

Prepared By:
   V. P. Sazonov

Experimental Data:   (Notes on the Nomenclature)
Upper critical solution temperatures of the systems nitromethane + 1,2,3-trialkyl glyceryl ether
t/°CT/KChemical Name
176.5449.7(Z,Z,Z)-1,2,3-Tris(9-octadecenyloxy)propane; C57H110O3; [10431-15-9]
178.0451.21-(Dodecyloxy)-2,3-bis(hexadecyloxy)propane; C47H96O3; [6076-43-3]
182.5455.71-(Dodecyloxy)-2-(hexadecyloxy)-3-(octadecyloxy)propane; C49H100O3; [6068-27-5]
183.0456.2(Z,Z)-1,2-Bis(9-octadecenyloxy)-3-(octadecyloxy)propane; C57H112O3; [10431-14-8]
185.5458.71-(Dodecyloxy)-2,3-bis(octadecyloxy)propane; C51H104O3; [5896-48-0]
186.0459.21,2,3-Tris(hexadecyloxy)propane; C51H104O3; [6110-59-4]
188.5461.7(Z)-1-(9-Octadecenyloxy)-2,3-bis(octadecyloxy)propane; C57H114O3; [13166-06-8]
196.0469.21,2,3-Tris(octadecyloxy)propane; C57H116O3; [6076-42-2]
   A microscope equipped with a heating stage1 was employed for determining UCST values. No further experimental details are given.

Source and Purity of Materials:
   (1) Fisher Scientific Co.; certified, No. N-98.
   (2) Synthesized as in Bauman and Mangold.2

Estimated Errors:
   Solubility: Not specified.
   Temperature: Not specified.
   Pressure: Not specified.

   1 H. H. O. Schmid, H. K. Mangold, and W. O. Lundberg, J. Am. Oil Chem. Soc. 42, 372 (1965).
   2 W. J. Baumann and H. K. Mangold, J. Org. Chem. 29, 3055 (1964).