IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

---

 Solubility System: Nitromethane with 2,2’-Iminobisethanol and N, N-Diethylethanamine

---

Components:
   (1) Nitromethane; CH3NO2 ; [75-52-5]  NIST Chemistry WebBook for detail
   (2) 2,2’-Iminobisethanol; C4H11NO2; [111-42-2]  NIST Chemistry WebBook for detail
   (3) N,N-Diethylethanamine; C6H15N; [121-44-8]  NIST Chemistry WebBook for detail

Original Measurements:
   Zhuravleva, I. K.; Zhuravlev, E. F. and Islamova, R. S.; Zh. Fiz. Khim. 48, 1863 (1974) *Deposited Doc., VINITI 855 (1974).

Variables:
   Temperature = 273 K to 344 K

Prepared By:
   V. P. Sazonov

Experimental Remarks:

   The solubility temperatures of the liquid phases were determined in ternary mixtures with a constant mass relationship of (1) and (3) as 10.0:90.0, 20.0:80.0, 30.1:69.9, 40.0:60.0, 50.0:50.0, 60.0:40.0, 80.0:20.0, 84.5:15.5, and 89.9:10.1, respectively. These data were also reported in a graphical form.

The compositions of two coexistent liquid phases at 20 °C are presented in graphical form.

Experimental Data:   (Notes on the Nomenclature)
  

Solubility temperatures of the liquid phases*

t/°C	T/K	Mass Fraction w1	Mass Fraction w2	Mole Fraction x1 (compiler)	Mole Fraction x2 (compiler)
0.0	273.2	0.085	0.150	0.134	0.138
4.5	277.7	0.089	0.115	0.139	0.105
11.3	284.5	0.093	0.070	0.146	0.064
16.5	289.7	0.095	0.051	0.149	0.046
25.2	298.4	0.096	0.040	0.150	0.036
11.3	284.5	0.273	0.273	0.222	0.242
20.0	293.2	0.218	0.218	0.236	0.192
25.5	298.7	0.193	0.193	0.243	0.169
30.4	303.6	0.169	0.169	0.250	0.147
34.5	307.7	0.150	0.150	0.255	0.130
41.4	314.6	0.126	0.126	0.261	0.109
53.2	326.4	0.100	0.100	0.268	0.086
65.3	338.5	0.090	0.095	0.269	0.082
3.9	277.1	0.106	0.648	0.168	0.597
4.6	277.8	0.098	0.676	0.156	0.626
5.0	278.2	0.114	0.621	0.180	0.568
6.3	279.5	0.120	0.600	0.188	0.547
8.4	281.6	0.128	0.574	0.200	0.520
8.8	282.0	0.082	0.728	0.132	0.683
13.3	286.5	0.071	0.763	0.116	0.721
14.5	287.7	0.143	0.525	0.221	0.470
19.5	292.7	0.154	0.488	0.236	0.434
20.0	293.2	0.063	0.792	0.103	0.754
24.7	297.9	0.060	0.800	0.098	0.763
25.7	298.9	0.167	0.445	0.253	0.392
28.8	302.0	0.057	0.809	0.094	0.773
39.2	302.4	0.189	0.371	0.282	0.322
45.0	318.2	0.198	0.343	0.294	0.295
55.0	328.2	0.207	0.312	0.305	0.267
60.0	333.2	0.211	0.300	0.310	0.256
70.8	344.0	0.215	0.287	0.315	0.244
34.1	307.3	0.131	0.672	0.205	0.610
35.2	308.4	0.116	0.710	0.183	0.651
37.6	310.8	0.111	0.723	0.176	0.665
38.0	311.2	0.147	0.632	0.227	0.567
40.9	314.1	0.158	0.605	0.242	0.539
43.8	317.0	0.098	0.754	0.157	0.700
49.4	322.6	0.090	0.776	0.145	0.725
52.4	325.6	0.083	0.793	0.134	0.745
57.0	330.2	0.078	0.805	0.127	0.759
65.0	338.2	0.071	0.823	0.116	0.780
0.0	273.2	0.490	0.020	0.615	0.015
5.6	278.8	0.494	0.012	0.618	0.009
10.2	283.4	0.500	0.000	0.624	0.000
0.5	273.7	0.589	0.018	0.704	0.013
5.1	278.3	0.594	0.010	0.708	0.007
8.3	281.5	0.600	0.000	0.713	0.000
4.6	277.8	0.518	0.353	0.647	0.256
5.5	278.7	0.294	0.633	0.417	0.521
6.8	280.0	0.502	0.373	0.632	0.273
9.2	282.4	0.309	0.614	0.434	0.501
11.0	284.2	0.469	0.414	0.601	0.308
11.8	285.0	0.324	0.595	0.451	0.481
13.6	286.8	0.441	0.449	0.574	0.339
14.0	287.2	0.341	0.574	0.470	0.459
15.4	288.6	0.414	0.482	0.547	0.370
15.9	289.1	0.381	0.524	0.513	0.410
12.6	285.8	0.279	0.670	0.399	0.557
18.1	291.3	0.628	0.257	0.742	0.176
19.0	292.2	0.303	0.641	0.427	0.525
21.2	294.4	0.607	0.282	0.725	0.195
24.6	297.8	0.332	0.607	0.460	0.489
26.4	299.6	0.557	0.341	0.682	0.243
28.0	301.2	0.352	0.583	0.482	0.464
28.3	301.5	0.530	0.373	0.658	0.269
30.0	303.2	0.493	0.416	0.624	0.306
31.4	304.6	0.433	0.488	0.567	0.371
31.4	304.6	0.401	0.526	0.534	0.407
0.5	273.7	0.247	0.725	0.361	0.615
8.8	282.0	0.256	0.715	0.372	0.603
14.6	287.8	0.805	0.104	0.875	0.066
15.0	288.2	0.270	0.700	0.389	0.585
20.0	293.2	0.280	0.689	0.401	0.572
25.2	298.4	0.778	0.135	0.856	0.086
25.6	298.8	0.301	0.665	0.425	0.546
32.1	305.3	0.740	0.177	0.829	0.115
33.1	306.3	0.335	0.627	0.464	0.504
37.6	310.8	0.688	0.235	0.790	0.157
38.2	311.4	0.367	0.592	0.499	0.467
39.7	312.9	0.653	0.274	0.763	0.186
41.1	314.3	0.404	0.550	0.538	0.425
42.0	315.2	0.618	0.313	0.735	0.216
43.6	316.8	0.574	0.361	0.698	0.255
43.8	317.0	0.458	0.490	0.592	0.368
44.4	317.6	0.502	0.441	0.634	0.323

Notes:
   ^*  This table was prepared by the compiler from the published curve of ternary system solubility.

Method/Apparatus/Procedure:
   Two methods were used. The solubility temperatures of liquid phases were determined by the synthetic method (Alekseev¹). The analytical method described in Nikurashina and Mertslin² was used for determining equilibrium liquid phase compositions. Samples from coexisting liquid phases at equilibrium were analyzed by refractometry. No experimental details given.

Source and Purity of Materials:
   (1) Source not specified; freshly distilled.
   (2) Source not specified, freshly distilled.
   (3) Source not specified, freshly distilled.

Estimated Errors:

   Temperature: Not specified.

References:
   ¹V. F. Alekseev, Zh. Russ. Fiz.-Khim. Ova 8, 249(1876).
   ²N. I. Nikurashina and R. V. Mertslin, Method of Secants (in Russian), Saratov University Press, 1969.

---

Distributed by the Office of Data and Informatics of the National Institute of Standards and Technology (NIST) Material Measurement Laboratory (MML).
Website is owned by NIST (an agency of the U.S. Department of Commerce)

---

Last updated: February 18, 2015 (Created: August 17, 2007)