IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

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 Solubility System: Nitromethane with 1-Hexanol and Water

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Components:
   (1) Nitromethane; CH3NO2 ; [75-52-5]  NIST Chemistry WebBook for detail
   (2) 1-Hexanol; C6H14O; [111-27-3]  NIST Chemistry WebBook for detail
   (3) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail

Original Measurements:
   Sazonov, V. P.; Markuzin, N. P. and Filippov, V. V.; Zh. Prikl. Khim. (Leningrad) 49, 784 (1976).

Variables:
   Temperature = 293 K and 313 K

Prepared By:
   V. P. Sazonov and N. V. Sazonov

Experimental Data:   (Notes on the Nomenclature)
  

Mutual solubility of nitromethane, 1-hexanol and water

t/°C	T/K	Mass Fraction w1	Mass Fraction w2	Mole Fraction x1 (compiler)	Mole Fraction x2 (compiler)
20.0	293.2	0.195	0.780	0.261	0.625
20.0	293.2	0.284	0.660	0.327	0.454
20.0	293.2	0.326	0.608	0.357	0.398
20.0	293.2	0.372	0.550	0.386	0.340
20.0	293.2	0.775	0.191	0.772	0.114
20.0	293.2	0.836	0.147	0.852	0.089
20.0	293.2	0.046	0.882	0.056	0.645
20.0	293.2	0.114	0.807	0.132	0.558
20.0	293.2	0.184	0.733	0.203	0.483
20.0	293.2	0.277	0.643	0.297	0.412
20.0	293.2	0.321	0.598	0.337	0.375
20.0	293.2	0.767	0.189	0.745	0.110
20.0	293.2	0.818	0.144	0.792	0.083
20.0	293.2	0.873	0.097	0.846	0.056
20.0	293.2	0.924	0.050	0.887	0.029
20.0	293.2	0.455	0.474	0.465	0.289
20.0	293.2	0.563	0.374	0.563	0.224
20.0	293.2	0.660	0.286	0.651	0.169
20.0	293.2	0.277	0.070	0.109	0.017
20.0	293.2	0.511	0.149	0.292	0.051
20.0	293.2	0.222	0.250	0.103	0.069
20.0	293.2	0.325	0.452	0.241	0.200
20.0	293.2	0.361	0.098	0.160	0.026
20.0	293.2	0.265	0.337	0.146	0.111
21.0	294.2	0.446	0.478	0.451	0.289
21.0	294.2	0.660	0.284	0.648	0.166
21.0	294.2	0.675	0.270	0.660	0.158
21.0	294.2	0.703	0.245	0.685	0.143
21.0	294.2	0.756	0.198	0.734	0.115
21.0	294.2	0.807	0.153	0.781	0.088
21.0	294.2	0.860	0.106	0.828	0.061
21.0	294.2	0.910	0.061	0.871	0.035
21.0	294.2	0.436	0.490	0.445	0.299
21.0	294.2	0.426	0.497	0.433	0.302
21.0	294.2	0.418	0.506	0.428	0.309
21.0	294.2	0.406	0.517	0.416	0.317
21.0	294.2	0.368	0.552	0.380	0.340
21.0	294.2	0.323	0.596	0.339	0.373
21.0	294.2	0.277	0.639	0.294	0.405
21.0	294.2	0.235	0.682	0.255	0.441
21.0	294.2	0.184	0.728	0.201	0.474
21.0	294.2	0.092	0.828	0.107	0.577
21.0	294.2	0.050	0.873	0.060	0.627
21.0	294.2	0.707	0.246	0.698	0.145
21.0	294.2	0.766	0.201	0.768	0.120
21.0	294.2	0.826	0.156	0.843	0.095
21.0	294.2	0.408	0.520	0.424	0.323
21.0	294.2	0.372	0.559	0.396	0.355
21.0	294.2	0.330	0.608	0.365	0.402
21.0	294.2	0.288	0.662	0.338	0.464
21.0	294.2	0.247	0.716	0.309	0.535
21.0	294.2	0.198	0.784	0.272	0.644
21.0	294.2	0.589	0.266	0.476	0.128
21.0	294.2	0.479	0.204	0.286	0.073
21.0	294.2	0.352	0.132	0.160	0.036
21.0	294.2	0.572	0.364	0.569	0.216
21.0	294.2	0.193	0.137	0.076	0.032
21.0	294.2	0.274	0.252	0.135	0.074
21.0	294.2	0.615	0.324	0.606	0.191
21.0	294.2	0.040	0.005	0.012	0.001
21.0	294.2	0.105	0.005	0.034	0.001
21.0	294.2	0.046	0.877	0.055	0.631
21.0	294.2	0.090	0.828	0.104	0.574
21.0	294.2	0.136	0.776	0.152	0.516
21.0	294.2	0.182	0.729	0.198	0.474
21.0	294.2	0.227	0.680	0.240	0.428
21.0	294.2	0.273	0.636	0.284	0.395
21.0	294.2	0.323	0.586	0.332	0.359
21.0	294.2	0.367	0.547	0.373	0.332
21.0	294.2	0.417	0.501	0.420	0.301
21.0	294.2	0.459	0.460	0.455	0.273
21.0	294.2	0.509	0.414	0.501	0.243
21.0	294.2	0.559	0.368	0.545	0.214
21.0	294.2	0.605	0.327	0.587	0.190
21.0	294.2	0.654	0.280	0.626	0.160
21.0	294.2	0.709	0.236	0.684	0.136
21.0	294.2	0.758	0.190	0.724	0.108
21.0	294.2	0.810	0.144	0.770	0.082
21.0	294.2	0.865	0.095	0.818	0.054
21.0	294.2	0.916	0.048	0.859	0.027
21.0	294.2	0.250	0.748	0.355	0.635
21.0	294.2	0.298	0.692	0.400	0.555
21.0	294.2	0.344	0.640	0.441	0.490
21.0	294.2	0.394	0.586	0.485	0.431
21.0	294.2	0.445	0.534	0.533	0.382
21.0	294.2	0.488	0.489	0.569	0.340
21.0	294.2	0.540	0.439	0.618	0.300
21.0	294.2	0.591	0.389	0.663	0.261
21.0	294.2	0.637	0.345	0.705	0.228
21.0	294.2	0.689	0.296	0.752	0.193
21.0	294.2	0.743	0.247	0.804	0.160
40.0	313.2	0.046	0.874	0.055	0.622
40.0	313.2	0.089	0.827	0.103	0.569
40.0	313.2	0.136	0.776	0.152	0.516
40.0	313.2	0.181	0.728	0.196	0.471
40.0	313.2	0.228	0.680	0.241	0.430
40.0	313.2	0.272	0.634	0.281	0.391
40.0	313.2	0.320	0.589	0.327	0.359
40.0	313.2	0.362	0.546	0.362	0.326
40.0	313.2	0.410	0.500	0.404	0.295
40.0	313.2	0.456	0.455	0.443	0.264
40.0	313.2	0.501	0.415	0.485	0.485
40.0	313.2	0.548	0.370	0.524	0.524
40.0	313.2	0.595	0.329	0.567	0.567
40.0	313.2	0.646	0.281	0.609	0.609
40.0	313.2	0.706	0.229	0.664	0.664
40.0	313.2	0.750	0.188	0.699	0.699
40.0	313.2	0.803	0.143	0.749	0.749
40.0	313.2	0.857	0.094	0.794	0.794
40.0	313.2	0.909	0.049	0.841	0.841

Method/Apparatus/Procedure:
   The solubility curves were determined by the titration method. No experimental details given.

Source and Purity of Materials:
   (1) Source not specified; pure grade reagent; dried and repeatedly distilled in a packed column of 25 theoretical plates; no impurities detectable by gas chromatography.
   (2) Source not specified; pure grade reagent; dried and repeatedly fractionated in a packed column of 50 theoretical plates; purity 99.95 mole % by GLC.
   (3) Twice distilled.

Estimated Errors:

   Temperature: Not specified.

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Last updated: February 18, 2015 (Created: August 17, 2007)